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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dobrzycki, Łukasz
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2020Magnesium tetraorganyl derivatives of group 13 metals as intermediate products in the synthesis of group 13 metal alkyls and arylscitations
- 2017Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
- 2015Aluminum, gallium and indium thiobenzoates: synthesis, characterization and crystal structurescitations
- 2015Role of Lewis bases in reactions of aluminum and gallium trialkyls with 2-mercaptobenzoxazolecitations
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article
Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
Abstract
2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In thisstudy, reactions of mbztH with Me3Ga and Me3In were examined. The products werecharacterized by NMR spectroscopy, elemental analyses, melting point and molecular weightdeterminations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In)was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon nonsymmetricaldinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfursand the other to two nitrogens.