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Basiak, Dariusz
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Publications (6/6 displayed)
- 2020Magnesium tetraorganyl derivatives of group 13 metals as intermediate products in the synthesis of group 13 metal alkyls and arylscitations
- 2019Ti2C MXene Modified with Ceramic Oxide and Noble Metal Nanoparticles: Synthesis, Morphostructural Properties, and High Photocatalytic Activitycitations
- 2019The toxicity in vitro of titanium dioxide nanoparticles modified with noble metals on mammalian cellscitations
- 2017Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
- 2015The Impact of Zeta Potential and Physicochemical Properties of TiO2-Based Nanocomposites on Their Biological Activitycitations
- 2014Nano-titanium oxide doped with gold, silver and palladium – synthesis and structural characterizationcitations
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article
Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
Abstract
2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In thisstudy, reactions of mbztH with Me3Ga and Me3In were examined. The products werecharacterized by NMR spectroscopy, elemental analyses, melting point and molecular weightdeterminations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In)was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon nonsymmetricaldinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfursand the other to two nitrogens.