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Ochal, Zbigniew
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2021Towards deeper understanding of multifaceted chemistry of magnesium alkylperoxidescitations
- 2017Lipase-catalyzed kinetic resolution approach toward enantiomerically enriched 1-(β-hydroxypropyl)indolescitations
- 2017Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
- 2015Role of Lewis bases in reactions of aluminum and gallium trialkyls with 2-mercaptobenzoxazolecitations
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article
Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
Abstract
2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In thisstudy, reactions of mbztH with Me3Ga and Me3In were examined. The products werecharacterized by NMR spectroscopy, elemental analyses, melting point and molecular weightdeterminations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In)was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon nonsymmetricaldinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfursand the other to two nitrogens.