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Pindelska, Edyta
Medical University of Warsaw
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article
Coordination modes of 2-mercapto-1,3-benzothiazolate in gallium and indium complexes
Abstract
2-Mercapto-1,3-benzothiazole (mbztH) may act as a chelating or bridging ligand. In thisstudy, reactions of mbztH with Me3Ga and Me3In were examined. The products werecharacterized by NMR spectroscopy, elemental analyses, melting point and molecular weightdeterminations. Formation of mononuclear chelating complexes Me2M(mbzt) (M = Ga, In)was observed in solutions. Crystallization of Me2M(mbzt) yielded uncommon nonsymmetricaldinuclear complexes Me4M2(mbzt)2, in which one metal is bonded to two sulfursand the other to two nitrogens.