• Rečnik, Aleksander
• Daneu, Nina
• Aksenov, Sergey
• Korsakov, Andrey
• Mikhailenko, Denis
• Rashchenko, Sergey
• Volkov, Sergey
• Banaev, Maksim V.
• Donskikh, Katerina G.

Abstract

<jats:p>It is generally accepted that aragonite crystals of biogenic origin are characterized by significantly higher twin densities compared to samples formed during geological processes. Based on our single crystal X-ray diffraction (SCXRD) and transmission electron microscopy (TEM) study of aragonite crystals from various localities, we show that in geological aragonites, the twin densities are comparable to those of the samples from crossed lamellar zones of molluscs shells. The high twin density is consistent with performed calculations, according to which the Gibbs free energy of twin-free aragonite is close to that of periodically twinned aragonite structure. In some cases, high twin densities result in the appearance of diffuse scattering in SCXRD patterns. The obtained TEM and optical micrographs show that besides the twin boundaries (TBs) of growth origin, there are also TBs and especially stacking faults that were likely formed as the result of local strain compensation. SCXRD patterns of the samples from Tazouta, in addition to diffuse scattering lines, show Debye arcs in the<jats:inline-formula><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline" overflow="scroll"><mml:mrow><mml:msup><mml:mi>a</mml:mi><mml:mo>∗</mml:mo></mml:msup><mml:msup><mml:mi>b</mml:mi><mml:mo>∗</mml:mo></mml:msup></mml:mrow></mml:math></jats:inline-formula>plane. These Debye arcs are present only on one side of the Bragg reflections and have an azimuthal extent of nearly 30°, making the whole symmetry of the diffraction pattern distinctly chiral, which has not yet been reported for aragonite. By analogy with biogenic calcite crystals, we associate these arcs with the presence of misoriented subgrains formed as a result of crystal twisting during growth.</jats:p>

Topics

• density
• impedance spectroscopy
• single crystal X-ray diffraction
• single crystal
• transmission electron microscopy
• stacking fault
• twinned