| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wang, Dong
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Engineered Anchor Peptide LCI with a Cobalt Cofactor Enhances Oxidation Efficiency of Polystyrene Microparticlescitations
- 2024Hydrogen diffusivity in X65 pipeline steel: Desorption and permeation studiescitations
- 2024Low-temperature process design for inversion mode n-channel thin-film-transistor on polycrystalline Ge formed by solid-phase crystallizationcitations
- 2024Controllable Si oxidation mediated by annealing temperature and atmosphere
- 2024Safe pipelines for hydrogen transportcitations
- 2024Integration of Multijunction Absorbers and Catalysts for Efficient Solar‐Driven Artificial Leaf Structures: A Physical and Materials Science Perspectivecitations
- 2023Gold nanosponges: fascinating optical properties of a unique disorder-dominated systemcitations
- 2022A dual functional chondro-inductive chitosan thermogel with high shear modulus and sustained drug release for cartilage tissue engineeringcitations
- 2022Controllable Si oxidation mediated by annealing temperature and atmospherecitations
- 2022Thin film nanostructuring at oblique angles by substrate patterning
- 2021Rapid fabrication and interface structure of highly faceted epitaxial Ni-Au solid solution nanoparticles on sapphirecitations
- 2019Investigation of a surface mounted pm machine concept with 3d-flux paths, modular stator and amorphous materialcitations
- 2018The effect of in-situ hydrogen plasma charging on the hydrogen embrittlement susceptibility of DP and TRIP steel
- 2016Solid-state dewetting of single- and bilayer Au-W thin films: unraveling the role of individual layer thickness, stacking sequence and oxidation on morphology evolutioncitations
- 2014A highly active and magnetically recoverable tris(triazolyl)-CuI catalyst for alkyne-azide cycloaddition reactionscitations
- 2013Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.citations
- 2005Polymerization and carbonization of high internal phase emulsionscitations
Places of action
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article
Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates.
Abstract
High-valent intermediates of binuclear nonheme iron enzymes are structurally unknown despite their importance for understanding enzyme reactivity. Nuclear resonance vibrational spectroscopy combined with density functional theory calculations has been applied to structurally well-characterized high-valent mono- and di-oxo bridged binuclear Fe model complexes. Low-frequency vibrational modes of these high-valent diiron complexes involving Fe motion have been observed and assigned. These are independent of Fe oxidation state and show a strong dependence on spin state. It is important to note that they are sensitive to the nature of the Fe2 core bridges and provide the basis for interpreting parallel nuclear resonance vibrational spectroscopy data on the high-valent oxo intermediates in the binuclear nonheme iron enzymes.