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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tsibouklis, John
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2020Inkjet printing of a thermolabile model drug onto FDM-printed substrates: formulation and evaluationcitations
- 2015An evaluation of the adhesion of solid oral dosage form coatings to the oesophaguscitations
- 2015An evaluation of the adhesion of solid oral dosage form coatings to the oesophaguscitations
- 2013Nanocomposites based on copolymers of fluorinated imide and polyhedral oligomeric silsesquioxane macromonomer: microstructure and morphology studiescitations
- 2011Multifunctional poly(alkyl methacrylate) films for dental carecitations
- 2011Mapping surface heterogeneity: the AFM-based approach
- 2011Ring opening metathesis polymerization of polyoctahedral oligomeric silsesquioxanes (POSS) incorporated oxanorbornene-5,6-dicarboximide: synthesis, characterization, and surface morphology of copolymerscitations
- 2011The effects of incorporated silicone oils and calcium carbonate on the resistance to settlement and the antifouling performance of a silicone elastomercitations
- 2010A thermogravimetric method for assessing the substantivity of polymer films on dentally relevant substratescitations
- 2010Towards the determination of surface energy at the nanoscale: a further assessment of the AFM-based approachcitations
- 2010A comparative study of surface energy data from atomic force microscopy and from contact angle goniometrycitations
- 2008Synthesis and characterization of low surface energy fluoropolymers as potential barrier coatings in oral carecitations
- 2004Friction coefficient mapping using the atomic force microscopecitations
- 2003Ultra-low surface energy polymerscitations
- 2002Poly(di-1H,1H,2H,2H-perfluoroalkylitaconate) filmscitations
- 2002Fluoropolymer coatings with inherent resistance to biofouling
- 2002Adhesion force mapping of polymer surfaces: factors influencing force of adhesioncitations
- 2002Adsorbed poly(ethyleneoxide)–poly(propyleneoxide) copolymers on synthetic surfaces: spectroscopy and microscopy of polymer structures and effects on adhesion of skin-borne bacteriacitations
- 2002A study of pyroelectric and dielectric properties of alternate layer fluorodeconoylmonoitaconate Langmuir-Blodgett filmscitations
- 2002Impact of Fluorination and Side-Chain Length on Poly(methylpropenoxyalkylsiloxane) and Poly(alkyl methacrylate) Solubility in Supercritical Carbon Dioxidecitations
- 2002Poly(di-1H,1H,2H,2H-perfluoroalkylitaconate) films:surface organisation phenomena, surface energy determinations and force of adhesion measurementscitations
- 2001Nanoindentation and adhesion-force-mapping studies of polymer blend films
- 2000Mapping the surface heterogeneity of a polymer blend: an adhesion-force-distribution study using the Atomic Force Microscopecitations
- 2000Poly(perfluoroalkyl methacrylate) film structures: surface organization phenomena, surface energy determinations, and force of adhesion measurementscitations
Places of action
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article
Ring opening metathesis polymerization of polyoctahedral oligomeric silsesquioxanes (POSS) incorporated oxanorbornene-5,6-dicarboximide: synthesis, characterization, and surface morphology of copolymers
Abstract
The synthesis and characterization of N-propyl-POSS-7-oxanorbornene-5,6-dicarboximide (NPONDI) and N-3-(trifluoromethyl)phenyl-7-oxanorbornene-5,6-dicarboximide (TFNDI) was reported. The synthesis of the POSS-based (co)polymers were accomplished by ring opening metathesis polymerization (ROMP). The monomers and polymers were characterized using FT-IR, 1H-, 13C-, 29Si-NMR, and GPC techniques. Thermal properties of TFNDI-NPONDI copolymers were evaluated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Transmission electron microscopic (TEM) analysis of optically transparent and flexible copolymer films revealed the presence of 50 nm-sized POSS agglomerates. Atomic force microscopy analysis of the film surface exhibited a modest increase in surface roughness of TFNDI-NPONDI copolymers as compared with homopoly[N-3(trifluoromethyl)phenyl-7-oxanorbornene-5,6-dicarboximide] (HTFNDI). The POSS incorporated polymers such as 1NPONDI, 2NPONDI, and 3NPONDI increased the hydrophobicity as compared with HTFNDI. This was measured by static contact angle analysis. The study focussed on the dispersion, surface morphology, and the microstructure of POSS in TFNDI-NPONDI copolymer as determined by scanning electron microscopy (SEM).