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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Baker, Murray
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Topics
Publications (6/6 displayed)
- 2021Poly(2-hydroxyethyl methacrylate) hydrogels doped with copper nanoparticlescitations
- 2011Modifying the response of a polymer-based quartz crystal microbalance hydrocarbon sensor with functionalized carbon nanotubescitations
- 2008Polydivinylferrocene surface modified electrode for measuring state-of-charge of lead-acid batterycitations
- 2004Solvent roles in metal ion coordination: the NiCl2 O-solvates, NiCl2 · 4MeOH, NiCl2 · 2MeOH · 0.5dioxan and NiCl2 · 2H2O · 2dioxancitations
- 2004Synthesis and Electrochemical Characterization of New Thioether- and Ferrocene-Containing Copolymerscitations
- 2001Synthesis and Electrochemical Behaviour of Vinylferrocene-Propylene Sulfide-Graft Copolymerscitations
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article
Synthesis and Electrochemical Characterization of New Thioether- and Ferrocene-Containing Copolymers
Abstract
Random copolymers containing both ferrocene groups and thioether groups were synthesized by free-radical copolymerization of vinylferrocene and 2-(methylthio)ethyl methacrylate, and the random nature of the copolymerization was confirmed by spectroscopic studies. Copolymers with ferrocene-to-thioether ratios of 8:1 and 1.2:1 were used to modify the surfaces of gold electrodes, and the behaviours of the resulting surface-modified electrodes were investigated by cyclic voltammetry. The SMEs based on the copolymers showed superior stability compared to SMEs based on poly(vinylferrocene), with the most stable SMEs being formed from the copolymer with the higher proportion of thioether groups.