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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Milichko, Valentin
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Topics
Publications (8/8 displayed)
- 2024Metal-organic framework single crystal for in-memory neuromorphic computing with a light controlcitations
- 2024Light-driven anisotropy of 2D metal-organic framework single crystal for repeatable optical modulationcitations
- 2024<i>In situ</i> tracking the phase change in metastable copper oxide thin film via thermal oxidation
- 2023The most sustainable high entropy alloys for the future
- 2023Nonlinear Metal–Organic Framework Crystals for Efficient Multicolor Coherent Optical Emissioncitations
- 2021Flexible Metal‐Organic Framework for Mechanical Sub Tbyte inch^(−2) Data Recording under Ambient Conditioncitations
- 2020Synergistic effect of plasma and laser processes in liquid for alloyed nanoparticles synthesiscitations
- 2017Multifold Emission Enhancement in Nanoimprinted Hybrid Perovskite Metasurfacescitations
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article
<i>In situ</i> tracking the phase change in metastable copper oxide thin film via thermal oxidation
Abstract
<jats:p>Phase change (PC) materials, such as metal oxides, possess high fundamental and applied importance for modern memory, sensor, and photonic devices. However, revealing the kinetics and mechanisms of PC and achieving the reversible and irreversible PC regimes are still a challenge. Here, we report on 200 nm films of metastable Cu4O3 obtained by magnetron sputtering. In situ structural and optical analyses during air annealing revealed the thermal induced PC from Cu4O3 to CuO. Combination of x-ray diffraction and optical transmittance with heating up to 450 °C allowed us to explore the PC rate and then to correlate it with classical nucleation and crystal growth mechanism. We have also revealed two regimes of PC, possessing reversible 12% (1.42–1.25 eV) and irreversible 220% (1.25–2.75 eV) direct bandgap tuning by temperature. The results, thereby, pave the way for controllable transformation of copper oxide thin films to achieve the desired microstructure and its functionality.</jats:p>