| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Floreano, Luca
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Origin of discrete donor–acceptor pair transitions in 2D Ruddlesden–Popper perovskitescitations
- 2024Origin of discrete donor–acceptor pair transitions in 2D Ruddlesden–Popper perovskitescitations
- 2024Stabilization versus competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surfacecitations
- 2024Band Structure Engineering in 2D Metal–Organic Frameworkscitations
- 2023Charge Transfer and Orbital Reconstruction at an Organic-Oxide Interface
- 2021Room-temperature on-spin-switching and tuning in a porphyrin-based multifunctional interface
- 2021Identification of Topotactic Surface‐Confined Ullmann‐Polymerizationcitations
- 2021Room‐Temperature On‐Spin‐Switching and Tuning in a Porphyrin‐Based Multifunctional Interfacecitations
- 2021Identification of Topotactic Surface-Confined Ullmann-Polymerizationcitations
- 2020Cobalt atoms drive the anchoring of Co-TPP molecules to the oxygen-passivated Fe(0 0 1) surfacecitations
- 2020Cobalt atoms drive the anchoring of Co-TPP molecules to the oxygen-passivated Fe(0 0 1) surfacecitations
- 2018On-surface synthesis of a 2D boroxine framework: A route to a novel 2D material?citations
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article
Origin of discrete donor–acceptor pair transitions in 2D Ruddlesden–Popper perovskites
Abstract
<jats:p>Two-dimensional (2D) van der Waals nanomaterials have attracted considerable attention for potential use in photonic and light–matter applications at the nanoscale. Thanks to their excitonic properties, 2D perovskites are also promising active materials to be included in devices working at room temperature. In this work, we study the presence of very narrow and spatially localized optical transitions in 2D lead halide perovskites by μ-photoluminescence and time-decay measurements. These discrete optical transitions are characterized by sub-millielectronvolt linewidths (≃120μeV) and long decay times (5–8 ns). X-ray photoemission and density-functional theory calculations have been employed to investigate the chemical origin of electronic states responsible of these transitions. The association of phenethylammonium with methylammonium cations into 2D Ruddlesden–Popper perovskites, (PEA)2(MA)n−1PbnI3n+1, particularly in phases with n≥2, has been identified as a mechanism of donor–acceptor pair (DAP) formation, corresponding to the displacement of lead atoms and their replacement by methylammonium. Ionized DAP recombination is identified as the most likely physical source of the observed discrete optical emission lines. The analysis of the experimental data with a simple model, which evaluates the Coulombic interaction between ionized acceptors and donors, returns a donor in Bohr radius of the order of ≃10 nm. The analysis of the spectral and electronic characteristics of these single donor–acceptor states in 2D perovskites is of particular importance both from the point of view of fundamental research, as well as to be able to link the emission of these states with new optoelectronic applications that require long-range optically controllable interactions.</jats:p>