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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fontanesi, Claudio
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Electrodeposition of Sn-Ru Alloys by Using Direct, Pulsed, and Pulsed Reverse Current for Decorative Applicationscitations
- 2024On the Electrochemical Growth of a Crystalline p–n Junction From Aqueous Solutionscitations
- 2023Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Aucitations
- 2023Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Aucitations
- 2023Spin-dependent electrochemistry and electrochemical enantioselective recognition with chiral methylated bis(ethylenedithio)-tetrathiafulvalenescitations
- 2023Chiral “doped” MOFs: an electrochemical and theoretical integrated studycitations
- 2022Magnetic Field Effect on the Handedness of Electrodeposited Heusler Alloycitations
- 2021Electrodeposition of Cu on PEDOT for a Hybrid Solid-State Electronic Devicecitations
- 2021Spin control using chiral templated nickelcitations
- 2019Highlighting spin selectivity properties of chiral electrode surfaces from redox potential modulation of an achiral probe under an applied magnetic fieldcitations
- 2018Electrochemistry of Metalloproteins Attached through Functional Self-Assembled Monolayers on Gold and Ferromagnetic Electrodescitations
- 2016Spin-Dependent Transport through Chiral Molecules Studied by Spin-Dependent Electrochemistrycitations
- 2014Effect of the Electric Field on the Structure of a Chiral Conductive Polymer Thin Film
- 2014Low band gap polymers for application in solar cells: synthesis and characterization of thienothiophene-thiophene copolymerscitations
- 2012A novel copolymer from benzodithiophene and alkylsulfanyl-bithiophene: Synthesis, characterization and application in polymer solar cellscitations
- 2012On the Hybrid Glassy Carbon Electrode/OligoThiophene/Ag(NP) Interfacecitations
- 2011Cobalt monolayer islands on Ag (111) for ORR catalysiscitations
- 2007Electrochemistry and spectroelectrochemistry of polypyridine ligands: A theoretical approachcitations
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article
Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Au
Abstract
<jats:p>A gold surface is functionalized by chemisorption of the enantiopure N,N′-bis-[2,2′;5′,2″]tert-thiophene-5-yl methylcyclohexane-1,2-diamine (2T3N), a chiral oligothiophene derivative, via overnight incubation in a 2T3N ethanol solution. The Au|2T3N interface is characterized by x-ray photoelectron circular dichroism and comparing x-ray photoemission spectroscopy and electro-desorption results. Charge transmission at the Au|2T3N| solution interface is characterized by recording the cyclic voltammetry of the Fe(III)/Fe(II) reversible redox couple, finding a charge transfer rate constant, k°, variation from 1 × 10−1 to 3.3 × 10−2 cm s−1, when comparing the bare Au and the Au|2T3N interfaces, respectively. The “anomalous” high value of k° found for the chiral Au|2T3N interface can be rationalized on the basis of the chiral-induced spin selectivity effect, as further proved by magnetic–conductive atomic force microscopy measurements at room temperature. A spin polarization of about 30% is found.</jats:p>