Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (83/83 displayed)

  • 2025Epitaxial growth of TiZrNbTaN films without external heating by high-power impulse magnetron sputtering1citations
  • 2024Reflective, polarizing, and magnetically soft amorphous neutron optics with $^{11}$B-enriched B$_4$C9citations
  • 2024Advanced film/substrate interface engineering for adhesion improvement employing time- and energy-controlled metal ion irradiation1citations
  • 2024Reflective, polarizing, and magnetically soft amorphous neutron optics with 11B-enriched B4C9citations
  • 2024High-power impulse magnetron sputter deposition of TiBx thin films : Effects of pulse length and peak current density5citations
  • 2024Electronic structure and thermoelectric properties of epitaxial Sc1−xVxNy thin films grown on MgO(001)1citations
  • 2023Dense and hard TiWC protective coatings grown with tungsten ion irradiation using WC-HiPIMS/TiC-DCMS co-sputtering technique without external heating10citations
  • 2023Towards lowering energy consumption during magnetron sputtering: Benefits of high-mass metal ion irradiation9citations
  • 2023Energy-efficient physical vapor deposition of dense and hard Ti-Al-W-N coatings deposited under industrial conditions11citations
  • 2023Morphology control in Ni/Ti multilayer neutron mirrors by ion-assisted interface engineering and B$_4$C incorporation9citations
  • 2023Determining role of W+ ions in the densification of TiAlWN thin films grown by hybrid HiPIMS/DCMS technique with no external heating4citations
  • 2023Thermoelectric properties and electronic structure of Cr(Mo,V)Nx thin films studied by synchrotron and lab-based x-ray spectroscopy2citations
  • 2023Morphology control in Ni/Ti multilayer neutron mirrors by ion-assisted interface engineering and B4C incorporation9citations
  • 2023Discovery of Guinier-Preston zone hardening in refractory nitride ceramics6citations
  • 2023Critical method evaluation refutes the Ar 2p signal of implanted Ar for referencing X-ray photoelectron spectra42citations
  • 2022High-entropy transition metal nitride thin films alloyed with Al : Microstructure, phase composition and mechanical properties33citations
  • 2022Dense, single-phase, hard, and stress-free Ti0.32Al0.63W0.05N films grown by magnetron sputtering with dramatically reduced energy consumption15citations
  • 2022Domain epitaxial growth of Ta3N5 film on c-plane sapphire substrate10citations
  • 2022Nano-columnar, self-organised NiCrC/a-C:H thin films deposited by magnetron sputtering4citations
  • 2022Microstructure, mechanical, and corrosion properties of Zr1-xCrxBy diboride alloy thin films grown by hybrid high power impulse/DC magnetron co-sputtering7citations
  • 2022The effect of the Nb concentration on the corrosion resistance of nitrogen-containing multicomponent TiZrTaNb-based films in acidic environments10citations
  • 2022Thermal, electrical, and mechanical properties of hard nitrogen-alloyed Cr thin films deposited by magnetron sputtering9citations
  • 2021Orthorhombic Ta3-xN5-yOy thin films grown by unbalanced magnetron sputtering : The role of oxygen on structure, composition, and optical properties9citations
  • 2021Dense Ti0.67Hf0.33B1.7 thin films grown by hybrid HfB2-HiPIMS/TiB2-DCMS co-sputtering without external heating15citations
  • 2021Toward energy-efficient physical vapor deposition : Routes for replacing substrate heating during magnetron sputter deposition by employing metal ion irradiation32citations
  • 2021Age hardening in superhard ZrB2-rich Zr1-xTaxBy thin films33citations
  • 2021Towards energy-efficient physical vapor deposition : Mapping out the effects of W+ energy and concentration on the densification of TiAlWN thin films grown with no external heating17citations
  • 2021Preparation and tunable optical properties of amorphous AlSiO thin films8citations
  • 2021Phase formation and structural evolution of multicomponent (CrFeCo)Ny films6citations
  • 2021Phase Transformation and Superstructure Formation in (Ti0.5, Mg0.5)N Thin Films through High-Temperature Annealing2citations
  • 2021Systematic compositional analysis of sputter-deposited boron-containing thin films37citations
  • 2020Oxidation behaviour of V2AlC MAX phase coatings55citations
  • 2020Microstructure and mechanical, electrical, and electrochemical properties of sputter-deposited multicomponent (TiNbZrTa)N-x coatings53citations
  • 2020Microstructure and mechanical, electrical, and electrochemical properties of sputter-deposited multicomponent (TiNbZrTa)N-x coatings53citations
  • 2020Growth of dense, hard yet low-stress Ti0.40Al0.27W0.33N nanocomposite films with rotating substrate and no external substrate heating19citations
  • 2020Effect of nitrogen content on microstructure and corrosion resistance of sputter-deposited multicomponent (TiNbZrTa)N-x films30citations
  • 2020Improving the high-temperature oxidation resistance of TiB2 thin films by alloying with Al96citations
  • 2020Effect of nitrogen content on microstructure and corrosion resistance of sputter-deposited multicomponent (TiNbZrTa)Nx films30citations
  • 2019Strategy for simultaneously increasing both hardness and toughness in ZrB2-rich Zr1-xTaxBy thin films59citations
  • 2019Reactive magnetron sputtering of tungsten target in krypton/trimethylboron atmosphere9citations
  • 2019Corrosion Resistant TiTaN and TiTaAlN Thin Films Grown by Hybrid HiPIMS/DCMS Using Synchronized Pulsed Substrate Bias with No External Substrate Heating6citations
  • 2019A simple model for non-saturated reactive sputtering processes15citations
  • 2019Synthesis and characterization of single-phase epitaxial Cr2N thin films by reactive magnetron sputtering19citations
  • 2019Control over the Phase Formation in Metastable Transition Metal Nitride Thin Films by Tuning the Al+ Subplantation Depth19citations
  • 2019Effect of impurities on morphology, growth mode, and thermoelectric properties of (111) and (001) epitaxial-like ScN films47citations
  • 2018Time evolution of ion fluxes incident at the substrate plane during reactive high-power impulse magnetron sputtering of groups IVb and VIb transition metals in Ar/N-240citations
  • 2018Reference binding energies of transition metal carbides by core-level x-ray photoelectron spectroscopy free from Ar+ etching artefacts88citations
  • 2018Controlling the B/Ti ratio of TiBx thin films grown by high-power impulse magnetron sputtering62citations
  • 2018Effect of ion-implantation-induced defects and Mg dopants on the thermoelectric properties of ScN41citations
  • 2017Control of the metal/gas ion ratio incident at the substrate plane during high-power impulse magnetron sputtering of transition metals in Ar26citations
  • 2017Core-level spectra and binding energies of transition metal nitrides by non-destructive x-ray photoelectron spectroscopy through capping layers148citations
  • 2017Unprecedented Al supersaturation in single-phase rock salt structure VAlN films by Al+ subplantation42citations
  • 2017Low-temperature growth of dense and hard Ti0.41Al0.51Ta0.08N films via hybrid HIPIMS/DC magnetron co-sputtering with synchronized metal-ion irradiation34citations
  • 2017Selectable phase formation in VAlN thin films by controlling Al+ subplantation depth19citations
  • 2017Comparative study of macro- and microtribological properties of carbon nitride thin films deposited by HiPIMS12citations
  • 2017Impact of B4C co-sputtering on structure and optical performance of Cr/Sc multilayer X-ray mirrors22citations
  • 2017Impact of B4C co-sputtering on structure and optical performance of Cr/Sc multilayer X-ray mirrors22citations
  • 2017Gas rarefaction effects during high power pulsed magnetron sputtering of groups IVb and VIb transition metals in Ar36citations
  • 2017Native target chemistry during reactive dc magnetron sputtering studied by ex-situ x-ray photoelectron spectroscopy9citations
  • 2016Improved adhesion of carbon nitride coatings on steel substrates using metal HiPIMS pretreatments42citations
  • 2016Nitrogen-doped bcc-Cr films: Combining ceramic hardness with metallic toughness and conductivity51citations
  • 2016Novel transparent Mg-Si-O-N thin films with high hardness and refractive index17citations
  • 2016Theoretical and experimental study of metastable solid solutions and phase stability within the immiscible Ag-Mo binary system17citations
  • 2016Peak amplitude of target current determines deposition rate loss during high power pulsed magnetron sputtering57citations
  • 2016A comparative study of direct current magnetron sputtering and high power impulse magnetron sputtering processes for CNX thin film growth with different inert gases23citations
  • 2016Rolling contact fatigue of bearing components coated with carbon nitride thin films23citations
  • 2016Venting temperature determines surface chemistry of magnetron sputtered TiN films110citations
  • 2015Synthesis and characterization of Zr2Al3C4 thin films11citations
  • 2015Strategy for tuning the average charge state of metal ions incident at the growing film during HIPIMS deposition37citations
  • 2015Control of Ti1-xSixN nanostructure via tunable metal-ion momentum transfer during HIPIMS/DCMS co-deposition59citations
  • 2015Low-temperature growth of low friction wear-resistant amorphous carbon nitride thin films by mid-frequency, high power impulse, and direct current magnetron sputtering18citations
  • 2014Novel strategy for low-temperature, high-rate growth of dense, hard, and stress-free refractory ceramic thin films57citations
  • 2014X-ray photoelectron spectroscopy analyses of the electronic structure of polycrystalline Ti1-xAlxN thin films with 0 < x < 0.9624citations
  • 2014Growth and properties of amorphous Ti-B-Si-N thin films deposited by hybrid HIPIMS/DC-magnetron co-sputtering from TiB2 and Si targets13citations
  • 2013Sputter-cleaned Epitaxial VxMo(1-x)Ny/MgO(001) Thin Films Analyzed by X-ray Photoelectron Spectroscopy: 3. Polycrystalline V0.49Mo0.51N1.027citations
  • 2013Sputter-cleaned Epitaxial VxMo(1-x)Ny/MgO(001) Thin Films Analyzed by X-ray Photoelectron Spectroscopy: 2. Single-crystal V0.47Mo0.53N0.9211citations
  • 2013Sputter-cleaned Epitaxial VxMo(1-x)Ny/MgO(001)Thin Films Analyzed by X-ray PhotoelectronSpectroscopy: 3. Polycrystalline V0.49Mo0.51N1.027citations
  • 2013Influence of inert gases on the reactive high power pulsed magnetron sputtering process of carbon-nitride thin films23citations
  • 2013Sputter-cleaned Epitaxial VxMo(1-x)Ny/MgO(001) Thin Films Analyzed by X-ray Photoelectron Spectroscopy: 1. Single-crystal V0.48Mo0.52N0.6412citations
  • 2012Metal versus rare-gas ion irradiation during Ti1-xAlxN film growth by hybrid high power pulsed magnetron/dc magnetron co-sputtering using synchronized pulsed substrate bias112citations
  • 2011Ti-Si-C-N Thin Films Grown by Reactive Arc Evaporation from Ti3SiC2 Cathodes20citations
  • 2011CF(x) thin solid films deposited by high power impulse magnetron sputtering: Synthesis and characterization43citations
  • 2010Time and energy resolved ion mass spectroscopy studies of the ion flux during high power pulsed magnetron sputtering of Cr in Ar and Ar/N-2 atmospheres123citations

Places of action

Chart of shared publication
Le Febvrier, Arnaud
15 / 47 shared
Magnusson, Roger
3 / 9 shared
Boyd, Robert
6 / 26 shared
Honnali, Sanath Kumar
2 / 6 shared
Lundin, Daniel
1 / 24 shared
Eklund, Per
20 / 131 shared
Nagy, Gyula
2 / 5 shared
Eriksson, Fredrik
11 / 29 shared
Stahn, Jochen
2 / 10 shared
Birch, Jens
11 / 73 shared
Thórarinsdóttir, Kristbjörg Anna
2 / 2 shared
Magnus, Fridrik
2 / 5 shared
Schwartzkopf, Matthias
2 / 59 shared
Ghafoor, Naureen
7 / 30 shared
Zubayer, Anton
2 / 8 shared
Glavic, Artur
2 / 8 shared
Stendahl, Sjoerd
2 / 5 shared
Palisaitis, Justinas
4 / 41 shared
Hultman, Lars
52 / 179 shared
Wicher, Bartosz
1 / 8 shared
Pshyk, Oleksandr
2 / 5 shared
Petruhins, Andrejs
1 / 12 shared
Sortica, Mauricio A.
3 / 9 shared
Zhirkov, Igor
4 / 8 shared
Rosen, Johanna
1 / 15 shared
Hellgren, Niklas
1 / 11 shared
Singh, Niraj Kumar
1 / 3 shared
Magnuson, Martin
3 / 20 shared
Chowdhury, Susmita
2 / 3 shared
Polcik, Peter
1 / 7 shared
Hsu, Tun-Wei
1 / 7 shared
Odén, Magnus
2 / 55 shared
Kolozsvári, Szilárd
1 / 5 shared
Petrov, Ivan
30 / 55 shared
Bakhit, Babak
18 / 27 shared
Lu, Jun
20 / 78 shared
Schell, Norbert
2 / 180 shared
Broekhuijsen, Sjoerd
2 / 3 shared
Li, Xiao
5 / 12 shared
Shu, Rui
7 / 17 shared
Hjort, Victor
1 / 3 shared
Pshyk, Oleksandr V.
1 / 1 shared
Sangiovanni, Davide Giuseppe
1 / 9 shared
Michler, J.
1 / 94 shared
Edwards, T. E. J.
1 / 7 shared
Pshyk, A. V.
1 / 3 shared
Vasylenko, A.
1 / 3 shared
Schweizer, P.
1 / 11 shared
Jõesaar, M. P. Johansson
1 / 1 shared
Kostov Gueorguiev, Gueorgui
2 / 3 shared
Hsiao, Ching-Lien
2 / 17 shared
Chang, Jui-Che
2 / 5 shared
Sandström, Per
1 / 6 shared
Lapitskaya, Vasilina
1 / 1 shared
Suszko, Tomasz
1 / 1 shared
Gulbiński, Witold
1 / 1 shared
Załęski, Karol
1 / 41 shared
Morgiel, Jerzy
1 / 23 shared
Mol, Arjan
1 / 64 shared
Kosari, Ali
1 / 14 shared
Dorri, Samira
1 / 6 shared
Paschalidou, Eirini-Maria
5 / 10 shared
Papaderakis, Athanasios A.
1 / 5 shared
Nyholm, Leif
5 / 15 shared
Belliard, Laurent
2 / 18 shared
Fournier, Daniele
2 / 7 shared
Djemia, Philippe
1 / 30 shared
Pallier, Camille
2 / 5 shared
Primetzhofer, Daniel
6 / 66 shared
Hu, Zhangjun
1 / 1 shared
Rosén, Johanna
11 / 54 shared
Schneider, Jochen M.
3 / 61 shared
Mráz, Stanislav
1 / 6 shared
Joesaar, M. P. Johansson
2 / 3 shared
Sortica, Mauritio A.
1 / 1 shared
Greene, Joseph E.
18 / 30 shared
Wu, Zhengtao
2 / 2 shared
Persson, Per O. Å.
1 / 22 shared
Jonsson, Bo
1 / 1 shared
Paul, Biplab
2 / 20 shared
Ali, Sharafat
2 / 17 shared
Gangaprasad Rao, Smita
3 / 7 shared
Gharavi, Mohammad Amin
2 / 6 shared
Armiento, Rickard
1 / 7 shared
Alling, Björn
3 / 50 shared
Ntemou, Eleni
1 / 5 shared
Pitthan, Eduardo
1 / 3 shared
Mraz, Stanislav
2 / 4 shared
Azina, Clio
1 / 19 shared
Hans, Marcus
2 / 38 shared
Lewin, Erik
2 / 30 shared
Rao, Smita G.
2 / 3 shared
Tengstrand, Olof
4 / 14 shared
Moro, Marcos V.
1 / 3 shared
Persson, Per O. A.
1 / 26 shared
Thörnberg, Jimmy
1 / 3 shared
Moro, Marcos Vinicius
1 / 2 shared
Högberg, Hans
4 / 37 shared
Engberg, David
1 / 2 shared
Tengdelius, Lina
1 / 7 shared
Broitman, Esteban
3 / 31 shared
Samuelsson, Mattias
1 / 7 shared
Herrera-Gomez, Alberto
1 / 1 shared
Chipatecua Godoy, Yuri
1 / 1 shared
Bustos, Erika
1 / 1 shared
Olaya Florez, Jairo
1 / 1 shared
Berg, Sören
1 / 1 shared
Nyberg, Tomas
1 / 7 shared
Fournier, D.
1 / 5 shared
Balke, B.
1 / 9 shared
Stilkerich, Nina
1 / 1 shared
Tureson, Nina
2 / 4 shared
Primetzhofer, D.
3 / 8 shared
Singh, Niraj
1 / 3 shared
Marteau, Marc
1 / 5 shared
Febvrier, Arnaud Le
1 / 5 shared
Cabioch, Thierry
1 / 6 shared
Soni, Ajay
1 / 6 shared
Van Nong, Ngo
1 / 50 shared
Jensen, Jens
11 / 37 shared
Schneider, J. M.
4 / 25 shared
Mraz, S.
4 / 4 shared
Hans, M.
1 / 4 shared
Fager, Hanna
2 / 6 shared
Mesic, B.
1 / 3 shared
Lemmer, O.
1 / 1 shared
Bolz, S.
1 / 3 shared
Koelker, W.
1 / 2 shared
Schiffers, Ch.
1 / 1 shared
Grillo, Stefano
1 / 2 shared
Schmidt, Susann
7 / 21 shared
Glenat, Hervè
1 / 1 shared
Bakoglidis, Konstantinos D.
4 / 11 shared
Andrew, Aquila
1 / 1 shared
Franz, Schäfers
1 / 1 shared
Gullikson, Eric
2 / 3 shared
Schaefers, Franz
1 / 1 shared
Jonson, Bo
1 / 6 shared
Sarakinos, Kostas
1 / 37 shared
Magnfält, Daniel
1 / 6 shared
Elofsson, Viktor
1 / 5 shared
Janzén, Erik
1 / 22 shared
Czigany, Zsolt
2 / 5 shared
Ivanov, Ivan Gueorguiev
1 / 14 shared
Wissting, Jonas
1 / 1 shared
Nedelcu, Ileana
1 / 1 shared
Ehret, Pascal
1 / 1 shared
Lai, Chung-Chuan
1 / 5 shared
Tucker, Mark
1 / 3 shared
Patscheider, J.
1 / 24 shared
Ektarawong, Annop
1 / 10 shared
Garbrecht, Magnus
1 / 7 shared
Ivanov, Ivan G.
1 / 7 shared
Lemmer, Oliver
2 / 4 shared
Bolz, Stephan
2 / 3 shared
Schiffers, Christoph
2 / 2 shared
Koelker, Werner
2 / 3 shared
Kindlund, Hanna
4 / 10 shared
Greene, Joe
1 / 1 shared
Greene, Joseph
1 / 1 shared
Sjölen, Jacob
1 / 2 shared
Eriksson, Anders
1 / 7 shared
Zhu, Jianqiang
1 / 3 shared
Johansson, Mats
1 / 25 shared
Czigany, Zs
1 / 1 shared
Gueorguiev Ivanov, Ivan
1 / 1 shared
Goyenola, Cecilia
1 / 5 shared
Chart of publication period
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2024
2023
2022
2021
2020
2019
2018
2017
2016
2015
2014
2013
2012
2011
2010

Co-Authors (by relevance)

  • Le Febvrier, Arnaud
  • Magnusson, Roger
  • Boyd, Robert
  • Honnali, Sanath Kumar
  • Lundin, Daniel
  • Eklund, Per
  • Nagy, Gyula
  • Eriksson, Fredrik
  • Stahn, Jochen
  • Birch, Jens
  • Thórarinsdóttir, Kristbjörg Anna
  • Magnus, Fridrik
  • Schwartzkopf, Matthias
  • Ghafoor, Naureen
  • Zubayer, Anton
  • Glavic, Artur
  • Stendahl, Sjoerd
  • Palisaitis, Justinas
  • Hultman, Lars
  • Wicher, Bartosz
  • Pshyk, Oleksandr
  • Petruhins, Andrejs
  • Sortica, Mauricio A.
  • Zhirkov, Igor
  • Rosen, Johanna
  • Hellgren, Niklas
  • Singh, Niraj Kumar
  • Magnuson, Martin
  • Chowdhury, Susmita
  • Polcik, Peter
  • Hsu, Tun-Wei
  • Odén, Magnus
  • Kolozsvári, Szilárd
  • Petrov, Ivan
  • Bakhit, Babak
  • Lu, Jun
  • Schell, Norbert
  • Broekhuijsen, Sjoerd
  • Li, Xiao
  • Shu, Rui
  • Hjort, Victor
  • Pshyk, Oleksandr V.
  • Sangiovanni, Davide Giuseppe
  • Michler, J.
  • Edwards, T. E. J.
  • Pshyk, A. V.
  • Vasylenko, A.
  • Schweizer, P.
  • Jõesaar, M. P. Johansson
  • Kostov Gueorguiev, Gueorgui
  • Hsiao, Ching-Lien
  • Chang, Jui-Che
  • Sandström, Per
  • Lapitskaya, Vasilina
  • Suszko, Tomasz
  • Gulbiński, Witold
  • Załęski, Karol
  • Morgiel, Jerzy
  • Mol, Arjan
  • Kosari, Ali
  • Dorri, Samira
  • Paschalidou, Eirini-Maria
  • Papaderakis, Athanasios A.
  • Nyholm, Leif
  • Belliard, Laurent
  • Fournier, Daniele
  • Djemia, Philippe
  • Pallier, Camille
  • Primetzhofer, Daniel
  • Hu, Zhangjun
  • Rosén, Johanna
  • Schneider, Jochen M.
  • Mráz, Stanislav
  • Joesaar, M. P. Johansson
  • Sortica, Mauritio A.
  • Greene, Joseph E.
  • Wu, Zhengtao
  • Persson, Per O. Å.
  • Jonsson, Bo
  • Paul, Biplab
  • Ali, Sharafat
  • Gangaprasad Rao, Smita
  • Gharavi, Mohammad Amin
  • Armiento, Rickard
  • Alling, Björn
  • Ntemou, Eleni
  • Pitthan, Eduardo
  • Mraz, Stanislav
  • Azina, Clio
  • Hans, Marcus
  • Lewin, Erik
  • Rao, Smita G.
  • Tengstrand, Olof
  • Moro, Marcos V.
  • Persson, Per O. A.
  • Thörnberg, Jimmy
  • Moro, Marcos Vinicius
  • Högberg, Hans
  • Engberg, David
  • Tengdelius, Lina
  • Broitman, Esteban
  • Samuelsson, Mattias
  • Herrera-Gomez, Alberto
  • Chipatecua Godoy, Yuri
  • Bustos, Erika
  • Olaya Florez, Jairo
  • Berg, Sören
  • Nyberg, Tomas
  • Fournier, D.
  • Balke, B.
  • Stilkerich, Nina
  • Tureson, Nina
  • Primetzhofer, D.
  • Singh, Niraj
  • Marteau, Marc
  • Febvrier, Arnaud Le
  • Cabioch, Thierry
  • Soni, Ajay
  • Van Nong, Ngo
  • Jensen, Jens
  • Schneider, J. M.
  • Mraz, S.
  • Hans, M.
  • Fager, Hanna
  • Mesic, B.
  • Lemmer, O.
  • Bolz, S.
  • Koelker, W.
  • Schiffers, Ch.
  • Grillo, Stefano
  • Schmidt, Susann
  • Glenat, Hervè
  • Bakoglidis, Konstantinos D.
  • Andrew, Aquila
  • Franz, Schäfers
  • Gullikson, Eric
  • Schaefers, Franz
  • Jonson, Bo
  • Sarakinos, Kostas
  • Magnfält, Daniel
  • Elofsson, Viktor
  • Janzén, Erik
  • Czigany, Zsolt
  • Ivanov, Ivan Gueorguiev
  • Wissting, Jonas
  • Nedelcu, Ileana
  • Ehret, Pascal
  • Lai, Chung-Chuan
  • Tucker, Mark
  • Patscheider, J.
  • Ektarawong, Annop
  • Garbrecht, Magnus
  • Ivanov, Ivan G.
  • Lemmer, Oliver
  • Bolz, Stephan
  • Schiffers, Christoph
  • Koelker, Werner
  • Kindlund, Hanna
  • Greene, Joe
  • Greene, Joseph
  • Sjölen, Jacob
  • Eriksson, Anders
  • Zhu, Jianqiang
  • Johansson, Mats
  • Czigany, Zs
  • Gueorguiev Ivanov, Ivan
  • Goyenola, Cecilia
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Theoretical and experimental study of metastable solid solutions and phase stability within the immiscible Ag-Mo binary system

  • Greczynski, Grzegorz
  • Sarakinos, Kostas
  • Magnfält, Daniel
  • Alling, Björn
  • Elofsson, Viktor
  • Högberg, Hans
Abstract

Metastable solid solutions are phases that are synthesized far from thermodynamic equilibrium and offer a versatile route to design materials with tailor-made functionalities. One of the most investigated classes of metastable solid solutions with widespread technological implications is vapor deposited ternary transition metal ceramic thin films (i.e., nitrides, carbides, and borides). The vapor-based synthesis of these ceramic phases involves complex and difficult to control chemical interactions of the vapor species with the growing film surface, which often makes the fundamental understanding of the composition-properties relations a challenging task. Hence, in the present study, we investigate the phase stability within an immiscible binary thin film system that offers a simpler synthesis chemistry, i.e., the Ag-Mo system. We employ magnetron co-sputtering to grow Ag1-xMox thin films over the entire composition range along with x-ray probes to investigate the films structure and bonding properties. Concurrently, we use density functional theory calculations to predict phase stability and determine the effect of chemical composition on the lattice volume and the electronic properties of Ag-Mo solid solutions. Our combined theoretical and experimental data show that Mo-rich films (x >= similar to 0.54) form bcc Mo-Ag metastable solid solutions. Furthermore, for Ag-rich compositions (x <= similar to 0.21), our data can be interpreted as Mo not being dissolved in the Ag fcc lattice. All in all, our data show an asymmetry with regards to the mutual solubility of Ag and Mo in the two crystal structures, i.e., Ag has a larger propensity for dissolving in the bcc-Mo lattice as compared to Mo in the fcc-Ag lattice. We explain these findings in light of isostructural short-range clustering that induces energy difference between the two (fcc and bcc) metastable phases. We also suggest that the phase stability can be explained by the larger atomic mobility of Ag atoms as compared to that of Mo. The mechanisms ...

Topics
  • density
  • impedance spectroscopy
  • surface
  • mobility
  • theory
  • thin film
  • aluminium
  • nitride
  • carbide
  • chemical composition
  • density functional theory
  • boride
  • clustering
  • dissolving
  • metastable phase
  • phase stability