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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Howdle, Steven M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024A facile one step route that introduces functionality to polymer powders for laser sinteringcitations
- 2023Modification of linear polyethylenimine with supercritical CO2 : from fluorescent materials to covalent cross-linkscitations
- 2022Antimicrobial ‘inks’ for 3D printing: block copolymer-silver nanoparticle composites synthesised using supercritical CO2citations
- 2021Amylose/cellulose nanofiber composites for all-natural, fully biodegradable and flexible bioplasticscitations
- 2020Starch/Poly(glycerol-adipate) Nanocomposites: A Novel Oral Drug Delivery Devicecitations
- 2020Low-temperature and purification-free stereocontrolled ring-opening polymerisation of lactide in supercritical carbon dioxidecitations
- 2019Hydrocarbon based stabilisers for the synthesis of cross-linked poly(2-hydroxyethyl methacrylate) particles in supercritical carbon dioxidecitations
- 2019Monitoring morphology evolution within block copolymer microparticles during dispersion polymerisation in supercritical carbon dioxidecitations
- 2014A high pressure cell for supercritical CO2 on-line chemical reactions studied with x-ray techniquescitations
- 2013Porous copolymers of ε-caprolactone as scaffolds for tissue engineeringcitations
- 2013Towards superhydrophobic coatings made by non-fluorinated polymers sprayed from a supercritical solutioncitations
- 2009Continuous flow supercritical chemical fluid deposition of optoelectronic quality CdScitations
- 2009Electrodeposition of metals from supercritical fluidscitations
- 2009Biocompatibility and osteogenic potential of human fetal femur-derived cells on surface selective laser sintered scaffoldscitations
- 2006Surface enhanced Raman scattering using metal modified microstructured optical fiber substratescitations
- 2006Surface enhanced Raman scattering using metal modified microstructured optical fibre substratescitations
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article
A high pressure cell for supercritical CO2 on-line chemical reactions studied with x-ray techniques
Abstract
<p>A versatile high pressure X-ray sample cell has been developed for conducting in situ time-resolved X-ray scattering experiments in the pressure and temperature regime required (pressures up to 210 bars and temperatures up to 120 degrees C) for chemical reactions in supercritical fluids. The large exit opening angle of the cell allows simultaneous performance of SAXS-WAXS experiments. Diamond windows are used in order to benefit from the combination of maximum strength, minimal X-ray absorption and chemical inertia. The sample cell can also be utilised for X-ray spectroscopy experiments over a wide range of photon energies. Results of the online synthesis of a block copolymer, poly(methyl methacrylate-block-poly(benzyl methacrylate), by Reversible Addition-Fragmentation Chain Transfer (RAFT) in a supercritical CO2 dispersion polymerisation will be discussed. The contribution of the density fluctuations, as function of temperature, to the X-ray scattering signal has been quantified in order to allow appropriate background subtractions. (C) 2014 AIP Publishing LLC.</p>