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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Deluca, Marco
Laboratori Guglielmo Marconi (Italy)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Synergistic Homovalent and Heterovalent Substitution Effects on Piezoelectric and Relaxor Behavior in Lead-Free BaTiO3 Ceramicscitations
- 2022Origin of Relaxor Behavior in Barium‐Titanate‐Based Lead‐Free Perovskitescitations
- 2022Influence of B content on microstructure, phase composition and mechanical properties of CVD Ti(B,N) coatingscitations
- 2022Raman Spectroscopy as a Key Method to Distinguish the Ferroelectric Orthorhombic Phase in Thin ZrO2-Based Filmscitations
- 2020Ceramic processing and multiferroic properties of the perovskite YMnO3-BiFeO3 binary systemcitations
- 2020B-site vacancy induced Raman scattering in BaTiO3-based ferroelectric ceramicscitations
- 2020Mechanical properties of zirconia ceramics biomimetically coated with calcium deficient hydroxyapatitecitations
- 2020Improving of ferroelectric and magnetic properties of Bi5Ti3FeO15 multiferroic materials with Y3+ and Co2+ partial substitution
- 2019FERROELECTRIC, MAGNETIC AND RAMAN SPECTRA MEASUREMENTS OF Bi5Ti3FeO15 AURIVILLIUS-BASED MULTIFERROIC MATERIALS
- 2019PHOTOCATALYTIC PROPERTIES OF BiFeO3 AND Bi5Ti3FeO15 BASED POWDERS
- 2018Remarkable impact of low BiYbO3 doping levels on the local structure and phase transitions of BaTiO3citations
- 2018Structure-property correlations and origin of relaxor behaviour in BaCexTi1-xO3citations
- 2018CuO Thin Films Functionalized with Gold Nanoparticles for Conductometric Carbon Dioxide Gas Sensingcitations
- 2016Integrated experimental and computational approach for residual stress investigation near through-silicon viascitations
- 2015Core-Shell Lead-Free Piezoelectric Ceramics: Current Status and Advanced Characterization of the Bi1/2Na1/2TiO3-SrTiO3 System
- 2015Processing-property relationship for solid-state synthesized CuAlO2 ceramic
- 2015Local distortions in nanostructured ferroelectric ceramics through strain tuningcitations
- 2015Chemical and structural effects on the high-temperature mechanical behavior of (1-x)(Na1/2Bi1/2)TiO3-xBaTiO(3) ceramicscitations
- 2014Nanostructuring effects in piezoelectric BiScO 3- PbTiO 3 ceramicscitations
- 2013Probing structural changes in Ca(1-x)Nd2x/3TiO3 ceramics by Raman spectroscopycitations
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article
Probing structural changes in Ca(1-x)Nd2x/3TiO3 ceramics by Raman spectroscopy
Abstract
Ceramics in the system Ca(1−x)Nd2x/3TiO3, intended for mobile communication applications, exhibit grossly non-linear variations in microwave dielectric properties with composition. There is evidence of a structural transition and the formation of vacancies on the A-site of the perovskite structure. High density, single phase perovskite Ca(1−x)Nd2x/3TiO3 ceramics have been prepared by the mixed oxide route. Raman spectroscopy was used to investigate the structural variations, which impact on dielectric properties. The Raman spectra show that with increasing Nd content, there is a transition from an ordered structure, to a disordered arrangement of cations and vacancies, and back to an ordered arrangement in Ca0.1Nd0.6TiO3. A structural phase transition from orthorhombic Pbnm to monoclinic C2/m coincides with the order-disorder transition at Ca0.1Nd0.6TiO3. Polarized Raman spectroscopy facilitated the assignment of the Raman modes and investigation of the role of importance of domain structures. Large variation in the plane angles was attributed to differences in domain structures. Differences in the angular dependence of the Raman modes with Nd content reflect changes in the preferred orientation of the domains from lamellar twins, to wedge shaped and back to lamellar twins.