| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mathevet, Fabrice
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Naphthalene Diimide‐Based Hydrogen‐Bonded Organic Framework for High Electrical Conductivity and Ammonia Sensor Applicationscitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2023Artificial p–n‐like Junction Based on Pure 2D Organic–Inorganic Halide Perovskite Structure Having Naphthalene Diimide Acceptor Moietiescitations
- 2022D-π-A-Type Pyrazolo[1,5-a]pyrimidine-Based Hole-Transporting Materials for Perovskite Solar Cells: Effect of the Functionalization Positioncitations
- 2018Strong Nonlinear Optical Response in the Visible Spectral Range with Epsilon‐Near‐Zero Organic Thin Filmscitations
- 2016<i>N</i>-channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
- 2016Chemical engineering of donor–acceptor liquid crystalline dyads and triads for the controlled nanostructuration of organic semiconductorscitations
- 2016textitN -channel field-effect transistors with an organic-inorganic layered perovskite semiconductorcitations
- 2012Influence of polymorphism on charge transport properties in isomers of fluorenone-based liquid crystalline semiconductorscitations
- 2011Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayerscitations
- 2010Diethynylbenzene-Based Liquid Crystalline Semiconductor for Solution-Processable Organic Thin-Film Transistorscitations
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article
Solution-growth kinetics and thermodynamics of nanoporous self-assembled molecular monolayers
Abstract
The temperature and concentration dependences of the self-assembly onto graphite from solution of a series of molecular building blocks able to form nanoporousstructures are analyzed experimentally by in situscanning tunneling microscopy. It is shown that the commonly observed coexistence of dense and nanoporous domains results from kinetic blockades rather than a thermodynamic equilibrium. The ripening can be favored by high densities of domain boundaries, which can be obtained by cooling the substrate before the nucleation and growth. Then ripening at higher-temperature yields large defect-free domains of a single structure. This thermodynamically stable structure can be either the dense or the nanoporous one, depending on the tecton concentration in the supernatant solution. A sharp phase transition from dense to honeycomb structures is observed at a critical concentration. This collective phenomenon is explained by introducing interactions between adsorbed molecules in the thermodynamic description of the whole system.