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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Guilmeau, E.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2021Effects of Grain Size on the Thermoelectric Properties of Cu2SnS3: An Experimental and First-Principles Studycitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2020Structure, microstructure and thermoelectric properties of germanite-type Cu22Fe8Ge4S32 compoundscitations
- 2018Substituting Copper with Silver in the BiMOCh Layered Compounds (M = Cu or Ag; Ch = S, Se, or Te) Crystal, Electronic Structure, and Optoelectronic Propertiescitations
- 2017The crucial role of selenium for sulphur substitution in the structural transitions and thermoelectric properties of Cu5FeS4 bornitecitations
- 2016Ba 6−3x Nd 8+2x Ti 18 O 54 Tungsten Bronze A New High-Temperature n-Type Oxide Thermoelectriccitations
- 2016Thermoelectric properties of TiS2 mechanically alloyed compoundscitations
- 2015Synthesis and thermoelectric properties in the 2D Ti 1 - x Nb x S 3 trichalcogenidescitations
- 2015On the effects of substitution, intercalation, non-stoichiometry and block layer concept in TiS 2 based thermoelectricscitations
- 2014Electron doping and phonon scattering in Ti1+xS2 thermoelectric compoundscitations
- 2014Thermoelectric properties of In0.2Co4Sb12 skutterudites with embedded PbTe or ZnO nanoparticlescitations
- 2013High temperature thermoelectric properties of CoSb3 skutterudites with PbTe inclusionscitations
- 2011Solution-based synthesis routes to thermoelectric Bi2Ca2Co1.7Oxcitations
- 2011Preparation of Ni-doped ZnO ceramics for thermoelectric applicationscitations
- 2010Transport and magnetic properties of Mo2.5Ru0.5Sb7−xTexcitations
- 2010High thermoelectric power factor in Fe-substituted Mo3Sb7citations
- 2010High thermoelectric power factor in Fe-substituted Mo.sub.3./sub.Sb.sub.7./sub.citations
- 2005Rietveld texture analysis of alumina ceramics by neutron diffractioncitations
- 2005Texture of alumina by neutron diffraction and SEM-EBSD
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article
Transport and magnetic properties of Mo2.5Ru0.5Sb7−xTex
Abstract
Transport properties including electrical resistivity, thermopower, and thermal conductivity of polycrystalline Mo2.5Ru0.5Sb7−xTex compounds for 0 ≤x ≤ 1 have been investigated in the 2–1000 K temperature range. Additional information on the concentrations and the scattering mechanisms of the charge carriers as well as on the magnetic properties has been obtained through Hall effect and magnetic susceptibility measurements performed in the 5–300 K temperature range. The enhancement in the Te content results in a decrease in the carrier concentration which is at the origin of the simultaneous increase in the electrical resistivity and thermopower. A single parabolic band model with acoustic phonon scattering enables to explain the compositional and temperature dependence of the thermopower while such a simple model fails to adequately describe the electronic thermal conductivity. This characteristic together with the unusual dependence of the thermal conductivity upon alloying might be a direct consequence of strong phonons-dimers interactions displayed by Mo3Sb7. Magnetic susceptibility data demonstrate that the antiferromagnetically-coupled dimers tend to disappear as x is enhanced, lending further support to a crucial role played by these interactions to understand the thermal transport in these materials. Low thermal conductivity coupled with high thermopower values result in a high dimensionless figure of merit ZT=0.7 at 1000 K in Mo2.5Ru0.5Sb6.5Te0.5 positioning this material as an interesting candidate for power generation applications.