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Baldi, Andrea
Vrije Universiteit Amsterdam
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2020Simple and Fast High-Yield Synthesis of Silver Nanowirescitations
- 2011Deposition of magnesium hydride thin films using radio frequency reactive sputteringcitations
- 2011Thin film metal hydrides for hydrogen storage applicationscitations
- 2010Mg/Ti multilayers: Structural and hydrogen absorption propertiescitations
- 2009Quasifree Mg-H thin filmscitations
- 2009Nanoscale composition modulations in MgyTi1-yHx thin film alloys for hydrogen storagecitations
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article
Quasifree Mg-H thin films
Abstract
The thermodynamics of hydrogen absorption in Pd-capped Mg films are strongly dependent on the magnesium thickness. In the present work, we suppress such dependency by inserting a thin Ti layer between Mg and Pd. By means of optical measurements, we show that the surface energy contribution to the destabilization of MgH(2) is negligible. The inserted Ti layer prevents Mg-Pd alloy formation at the Mg/Pd interface, leading to quasifree Mg films and enhancing the kinetics of hydrogen desorption. Our observations are important for the development of thin film devices.