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Proffit, D. L.
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article
Influence of symmetry mismatch on heteroepitaxial growth of perovskite thin films
Abstract
Epitaxial thin films of (110) orthorhombic CaRuO(3) grown on orthorhombic (110) NdGaO(3) and cubic (001) (LaAlO(3))(0.3)-(Sr(2)AlTaO(6))(0.7) (LSAT) substrates serve as a model system isolating the influence of oxygen octahedron distortion on epitaxial growth of thin films. CaRuO(3) grows as a coherent single crystal on NdGaO(3) with an atomically smooth surface, whereas CaRuO(3) on LSAT is multidomain with a rough surface despite the equivalent film stoichoimetry and average lattice mismatch between CaRuO(3) and the substrates. Anisotropic metallic resistivity of the single crystal CaRuO(3) was observed at 10 K with different electrical behaviors as a function of temperature for [(1) over bar 10] and [001] in-plane directions. (C) 2008 American Institute of Physics.