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- 2012Colloidal Anisotropic ZnO–Fe@Fe x O y Nanoarchitectures with Interface-Mediated Exchange-Bias and Band-Edge Ultraviolet Fluorescencecitations
- 2012Antibacterial Surface Coatings from Zinc Oxide Nanoparticles Embedded in Poly( N ‐isopropylacrylamide) Hydrogel Surface Layerscitations
- 2009[KCl3{H2dabco}]: A Unique 3-D Charge-Assisted Hydrogen-Bonded Hybrid Network of Anionic KCl3 Chains and Organic Cationscitations
- 2004A two-dimensional magnetic architecture with bridging polynitrile and 2,2′-bipyrimidine ligandscitations
- 2004A two-dimensional magnetic architecture with bridging polynitrile and 2,2′-bipyrimidine ligandscitations
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A two-dimensional magnetic architecture with bridging polynitrile and 2,2′-bipyrimidine ligands
Abstract
A new polymeric, two-dimensional compound [Co2(bpym)(dcne) 4 (H2O)2] (1) (dcne = [(CN)2CC(O) OEt)]- = 2,2-dicyano-1-ethoxyethenolate anion and bpym = 2,2'-bipyrimidine) has been synthesized and characterized by X-ray crystallography. The structure is monoclinic space group P21/a and consists of two-dimensional networks of octahedrally coordinated Co(II) ions, bridged by bis-bidentate 2,2'-bipyrimidine and μ2-dcne anions. Magnetic measurements revealed a broad maximum in the xm vs T plot at 20 K which is characteristic of antiferromagnetic exchange between the high spin cobalt(II) centres. © EDP Sciences.