| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Thompson, Stephen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworkscitations
- 2019Sub-lattice polarization states in anti-ferroelectrics and their relaxation processcitations
- 2017New synchrotron powder diffraction facility for long-duration experimentscitations
- 2015Advances in synchrotron x-ray diffraction and transmission electron microscopy techniques for the investigation of microstructure evolution in proton- and neutron-irradiated zirconium alloyscitations
- 2014The fabrication of a bifunctional oxygen electrode without carbon components for alkaline secondary batteriescitations
- 2011High-resolution synchrotron X-ray diffraction studies of size and strain effects in a complex Al–Fe–Cr–Ti alloy
- 2007A novel approach to dynamic modelling of polymer extrusion for improved process controlcitations
- 2007A Soft Sensor for viscosity control of polymer extrusioncitations
- 2004The structure and thermal expansion behaviour of ikaite, CaCO3. 6H2O, from T = 114 to T = 293 Kcitations
Places of action
| Organizations | Location | People |
|---|
article
Electron Beam and Thermal Stabilities of MFM-300(M) Metal-Organic Frameworks
Abstract
This work reports the thermal and electron beam stabilities of a series of isostructural metal-organic frameworks (MOFs) of type MFM-300(M), where M = Al, Ga, In, or Cr. MFM-300(Cr) was most electron beam stable, having an unusually high critical electron fluence of 1111 e-·Å-2 while the Group 13 element MOFs were found to be less stable. Within Group 13, MFM-300(Al) had the highest critical electron fluence of 330 e-·Å-2, compared to 189 e-·Å-2 and 147 e-·Å-2 for the Ga and In MOFs respectively. For all four MOFs, electron beam-induced structural degradation was independent of crystal size and was highly anisotropic, with the one-dimensional pore channels being the most stable, although the length and width of the channels decreased during electron beam irradiation. Notably, MFM-300(Cr) was found to retain crystallinity while shrinking up to 10%. Thermal stability was studied using in situ synchrotron X-ray diffraction at elevated temperature which revealed critical temperatures for crystal degradation to be 605, 570, 490 and 480°C for Al, Cr, Ga, and In, respectively. The pore channel diameters contracted by ~0.5% on desorption of solvent species but thermal degradation at higher temperatures was isotropic. The observed electron stabilities were found to scale with the relative inertness of the cations and correlate well to the measured lifetime of the materials when used as photocatalysts.<br/><br/>