| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mendes, Adélio
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (44/44 displayed)
- 2023C-N linked donor type porphyrin derivatives: unrevealed hole-transporting materials for efficient hybrid perovskite solar cellscitations
- 2023The effect of Bi doping on the thermal conductivity of ZnO and ZnO:Al thin films
- 2022PEDOT-graphene counter-electrode for solar and improved artificial light conversion in regular, bifacial and FTO-less cobalt mediated DSSCscitations
- 2022Vanadium (oxy)nitride as a new category of anode for direct ammonia solid oxide fuel cells cellscitations
- 2022An all-in-one approach for self-powered sensing: a methanol fuel cell modified with a molecularly imprinted polymer for cancer biomarker detectioncitations
- 2021Graded morphologies and the performance of PffBT4T-2OD:PC71BM devices using additive choicecitations
- 2021Production of hydrogen from methanol steam reforming using CuPd/ZrO2 catalysts - Influence of the catalytic surface on methanol conversion and CO selectivitycitations
- 2021A passive direct methanol fuel cell as transducer of an electrochemical sensor, applied to the detection of carcinoembryonic antigencitations
- 2021Passivation of the TiO2 Surface and Promotion of N719 Dye Anchoring with Poly(4-vinylpyridine) for Efficient and Stable Dye-Sensitized Solar Cellscitations
- 2020Accelerated aging of anticorrosive coatings: Two-stage approach to the AC/ DC/AC electrochemical methodcitations
- 2019Double-walled iron oxide nanotubes via selective chemical etching and Kirkendall processcitations
- 2019Integrated design of hematite and dye-sensitized solar cell for unbiased solar charging of an organic-inorganic redox flow batterycitations
- 2019Development of hermetic glass frit encapsulation for perovskite solar cellscitations
- 2018Furanoate-Based Nanocomposites: A Case Study Using Poly(Butylene 2,5-Furanoate) and Poly(Butylene 2,5-Furanoate)-co-(Butylene Diglycolate) and Bacterial Cellulosecitations
- 2018Embedded Chromium Current Collectors for Efficient and Stable Large Area Dye Sensitized Solar Cellscitations
- 2018Recent developments in the optimization of the bulk heterojunction morphology of polymer: Fullerene solar cellscitations
- 2018Combined in-depth X-ray Photoelectron Spectroscopy and Time-of-Flight Secondary Ion Mass Spectroscopy study of the effect of deposition pressure and substrate bias on the electrical properties and composition of Ga-doped ZnO thin films grown by magnetron sputteringcitations
- 2018Polyol synthesis of reduced graphene oxide supported platinum electrocatalysts for fuel cells: Effect of Pt precursor, support oxidation level and pHcitations
- 2017Low temperature hermetic laser-assisted glass frit encapsulation of soda lime glass substratescitations
- 2017Highly efficient SiO2/TiO2 composite photoelectrodes for dye-sensitized solar cellscitations
- 2017Development of stable current collectors for large area dye-sensitized solar cellscitations
- 2017Heat integration of methanol steam reformer with a high-temperature polymeric electrolyte membrane fuel cellcitations
- 2017TiO2-coated window for facilitated gas evolution in PEC solar water splittingcitations
- 2017Synergetic integration of a methanol steam reforming cell with a high temperature polymer electrolyte fuel cellcitations
- 2017TiO2/reduced graphene oxide composites for photocatalytic degradation in aqueous and gaseous mediumcitations
- 2016The influence of impurities in high temperature polymer electrolyte membrane fuel cells performancecitations
- 2016Intensification of Photocatalytic Pollutant Abatement in Microchannel Reactor Using TiO2 and TiO2-Graphenecitations
- 2016Extremely stable bare hematite photoanode for solar water splittingcitations
- 2016Photoelectrochemical water splitting using WO3 photoanodes: the substrate and temperature rolescitations
- 2015Composite-alumina-carbon molecular sieve membranes prepared from novolac resin and boehmite. Part I: Preparation, characterization and gas permeation studiescitations
- 2015Transparent Cuprous Oxide Photocathode Enabling a Stacked Tandem Cell for Unbiased Water Splittingcitations
- 2014Evaluation of Bonding Performance of Amino Polymers Using ABEScitations
- 2014Laser assisted dye-sensitized solar cell sealing: From small to large cells areascitations
- 2014Hematite photoelectrodes for water splitting: evaluation of the role of film thickness by impedance spectroscopytcitations
- 2013Use of Segmented Cell Operated in Hydrogen Recirculation Mode to Detect Water Accumulation in PEMFCcitations
- 2012Glass-Glass Laser-Assisted Glass Frit Bondingcitations
- 2012Laser assisted glass frit sealing of dye-sensitized solar cellscitations
- 2011A dynamic model for high temperature polymer electrolyte membrane fuel cellscitations
- 2011Segmented polymer electrolyte membrane fuel cells-A reviewcitations
- 2011Phenomenological modeling of dye-sensitized solar cells under transient conditionscitations
- 2011An Electrochemical Impedance Spectroscopy Study of Polymer Electrolyte Membrane Fuel Cells Electrocatalyst Single Wall Carbon Nanohorns-Supportedcitations
- 2011The influence of CO on the current density distribution of high temperature polymer electrolyte membrane fuel cellscitations
- 2011Use of single wall carbon nanohorns in polymeric electrolyte fuel cellscitations
- 2010Proton conductive membranes based on doped sulfonated polytriazolecitations
Places of action
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document
C-N linked donor type porphyrin derivatives: unrevealed hole-transporting materials for efficient hybrid perovskite solar cells
Abstract
A new series of Zn(II) and Cu(II)-based porphyrin complexes 5a and 5b doubly functionalised with carbazole units were developed to be used as hole-transporting materials (HTMs) in perovskite solar cells (PSCs). These complexes were obtained via a nucleophilic substitution reaction mediated by PhI(OAc)2/ NaAuCl4 center dot 2H(2)O, or using C-N transition metal-assisted coupling. The hole extraction capability of 5a and 5b was assessed using cyclic voltammetry; this study confirmed the better alignment of the Zn(II) complex 5a with the perovskite valence band level, compared to the Cu(II) complex 5b. The optimised geometry and molecular orbitals of both complexes also corroborate the higher potential of 5a as a HTM. Photoluminescence characterisation showed that the presence of 5a and 5b as HTMs on the perovskite surface resulted in the quenching of the emission, matching the hole transfer phenomenon. The photovoltaic performance was evaluated and compared with those of reference cells made with the standard HTM spiro-OMeTAD. The optimised 5-based devices showed improvements in all photovoltaic characteristics; their open circuit voltage (Voc) reached close to 1 V and short-circuit current density ( Jsc) values were 13.79 and 9.14 mA cm(-2) for 5a and 5b, respectively, disclosing the effect of the metallic centre. A maximum power conversion efficiency (PCE) of 10.01% was attained for 5a, which is 65% of the PCE generated by using the spiro-OMeTAD reference. This study demonstrates that C-N linked donor-type porphyrin derivatives are promising novel HTMs for developing efficient and reproducible PSCs.