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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Asghar, Muhammad Imran
Tampere University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024A novel CuFe2O4 ink for the fabrication of low-temperature ceramic fuel cell cathodes through inkjet printingcitations
- 2023A novel CuFe2O4 ink for the fabrication of low-temperature ceramic fuel cell cathodes through inkjet printingcitations
- 2023A novel CuFe2O4 ink for the fabrication of low-temperature ceramic fuel cell cathodes through inkjet printingcitations
- 2022Demonstrating the potential of iron-doped strontium titanate electrolyte with high-performance for low temperature ceramic fuel cellscitations
- 2022Perovskite Al-SrTiO<sub>3</sub> semiconductor electrolyte with superionic conduction in ceramic fuel cellscitations
- 2022A-site deficient semiconductor electrolyte Sr1−xCoxFeO3−δ for low-temperature (450-550 °C) solid oxide fuel cellscitations
- 2022Perovskite Al-SrTiO3 semiconductor electrolyte with superionic conduction in ceramic fuel cellscitations
- 2022Development and characterization of highly stable electrode inks for low-temperature ceramic fuel cellscitations
- 2022Development and characterization of highly stable electrode inks for low-temperature ceramic fuel cellscitations
- 2021Semiconductor Nb-Doped SrTiO3-δPerovskite Electrolyte for a Ceramic Fuel Cellcitations
- 2021Interface engineering of bi-layer semiconductor SrCoSnO3-δ-CeO2-δ heterojunction electrolyte for boosting the electrochemical performance of low-temperature ceramic fuel cellcitations
- 2021Systematic analysis on the effect of sintering temperature for optimized performance of li0.15ni0.45zn0.4o2-gd0.2ce0.8o2-li2co3-na2co3-k2co3 based 3d printed single-layer ceramic fuel cellcitations
- 2021Tailoring triple charge conduction in BaCo0.2Fe0.1Ce0.2Tm0.1Zr0.3Y0.1O3−δ semiconductor electrolyte for boosting solid oxide fuel cell performancecitations
- 2021Novel Perovskite Semiconductor Based on Co/Fe-Codoped LBZY (La0.5Ba0.5Co0.2Fe0.2Zr0.3Y0.3O3-δ) as an Electrolyte in Ceramic Fuel Cellscitations
- 2021Electrochemical Properties of a Dual-Ion Semiconductor-Ionic Co0.2Zn0.8O-Sm0.20Ce0.80O2-δComposite for a High-Performance Low-Temperature Solid Oxide Fuel Cellcitations
- 2021Promoted electrocatalytic activity and ionic transport simultaneously in dual functional Ba0.5Sr0.5Fe0.8Sb0.2O3-δ-Sm0.2Ce0.8O2-δ heterostructurecitations
- 2021Investigation of factors affecting the performance of a single-layer nanocomposite fuel cellcitations
- 2020Semiconductor Fe-doped SrTiO3-δ perovskite electrolyte for low-temperature solid oxide fuel cell (LT-SOFC) operating below 520 °Ccitations
- 2018Wide bandgap oxides for low-temperature single-layered nanocomposite fuel cellcitations
- 2017Advanced low-temperature ceramic nanocomposite fuel cells using ultra high ionic conductivity electrolytes synthesized through freeze-dried method and solid-routecitations
- 2016Investigation of LiNiCuZn-oxide electrodes prepared by different methodscitations
Places of action
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article
A-site deficient semiconductor electrolyte Sr1−xCoxFeO3−δ for low-temperature (450-550 °C) solid oxide fuel cells
Abstract
<p>Fast ionic conduction at low operating temperatures is a key factor for the high electrochemical performance of solid oxide fuel cells (SOFCs). Here an A-site deficient semiconductor electrolyte Sr<sub>1−x</sub>Co<sub>x</sub>FeO<sub>3−δ</sub> is proposed for low-temperature solid oxide fuel cells (LT-SOFCs). A fuel cell with a structure of Ni/NCAL-Sr<sub>0.7</sub>Co<sub>0.3</sub>FeO<sub>3−δ</sub>-NCAL/Ni reached a promising performance of 771 mW cm<sup>−2</sup> at 550 °C. Moreover, appropriate doping of cobalt at the A-site resulted in enhanced charge carrier transportation yielding an ionic conductivity of >0.1 S cm<sup>−1</sup> at 550 °C. A high OCV of 1.05 V confirmed that neither short-circuiting nor power loss occurred during the operation of the prepared SOFC device. A modified composition of Sr<sub>0.5</sub>Co<sub>0.5</sub>FeO<sub>3−δ</sub> and Sr<sub>0.3</sub>Co<sub>0.7</sub>FeO<sub>3−δ</sub> also reached good fuel cell performance of 542 and 345 mW cm<sup>−2</sup>, respectively. The energy bandgap analysis confirmed optimal cobalt doping into the A-site of the prepared perovskite structure improved the charge transportation effect. Moreover, XPS spectra showed how the Co-doping into the A-site enhanced O-vacancies, which improve the transport of oxide ions. The present work shows that Sr<sub>0.7</sub>Co<sub>0.3</sub>FeO<sub>3−δ</sub> is a promising electrolyte for LT-SOFCs. Its performance can be boosted with Co-doping to tune the energy band structure.</p>