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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bernot, Kevin
Institut National des Sciences Appliquées de Rennes
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Halogen-Bonds-Based Strategy for the Design of Highly Luminescent Lanthanide Coordination Polymers as Taggants for Plastic Waste Sortingcitations
- 2023Metallogels: a novel approach for the nanostructuration of single-chain magnetscitations
- 2022Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compoundscitations
- 2022Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compoundscitations
- 2022Synthesis, Crystal Structure, and Luminescence Properties of the Iso-Reticular Series of Lanthanide Coordination Polymers Synthesized from Hexa-Lanthanide Molecular Precursorscitations
- 2022Microwave-assisted synthesis of lanthanide coordination polymers with 2-bromobenzoic acid as ligand from hexa-lanthanide molecular precursorscitations
- 2021Highly Luminescent Europium-Based Heteroleptic Coordination Polymers with Phenantroline and Glutarate Ligandscitations
- 2021Hexanuclear Molecular Precursors as Tools to Design Luminescent Coordination Polymers with Lanthanide Segregationcitations
- 2020Luminescence properties of lanthanide complexes-based molecular alloyscitations
- 2020Luminescence properties of lanthanide complexes-based molecular alloyscitations
- 2019Hetero-hexalanthanide Complexes: A New Synthetic Strategy for Molecular Thermometric Probescitations
- 2019A new family of lanthanide-based coordination polymers with azoxybenzene-3,3′,5,5′-tetracarboxylic acid as ligandcitations
- 2019Microcrystalline Core–Shell Lanthanide-Based Coordination Polymers for Unprecedented Luminescent Propertiescitations
- 2018trans to cis photo-isomerization in merocyanine dysprosium and yttrium complexescitations
- 2017Lanthanide coordination polymers with 1,2-phenylenediacetatecitations
- 2017High Brightness and Easy Color Modulation in Lanthanide-Based Coordination Polymers with 5-Methoxyisophthalate as Ligand: Toward Emission Colors Additive Strategycitations
- 2015Extending the lanthanide–terephthalate system: Isolation of an unprecedented Tb(III)-based coordination polymer with high potential porosity and luminescence propertiescitations
- 2014Heteronuclear lanthanide-based coordination polymers exhibiting tunable multiple emission spectracitations
- 2013Synthesis, Crystal Structure and Luminescent Properties of New Lanthanide-Containing Coordination Polymers Involving 4,4'-oxy-bis-benzoate as Ligand.citations
- 2013Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymerscitations
- 2013Color and Brightness Tuning in Heteronuclear Lanthanide Terephthalate Coordination Polymerscitations
- 2011Lanthanide Aminoisophthalate Coordination Polymers: A Promising System for Tunable Luminescent Propertiescitations
- 2008New lanthanide based coordination polymers with high potential porosity.citations
Places of action
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article
Metallogels: a novel approach for the nanostructuration of single-chain magnets
Abstract
In this study we demonstrate that single-chain magnets (SCMs) can be assembled in gel phase and transferred intact on surface. We take advantage of a family of SCMs based on Tb(III) ions and nitronyl-nitroxides radicals functionalized with short alkyl chains known to form crystalline supramolecular nanotubes interacting with heptane acting as crystallizing solvent. When the radicals are functionalized with long aliphatic chains a robust gel is formed with similar structural and functional properties respect to its crystalline parent. Indeed, a small-angle X-ray scattering (SAXS) study unambiguously demonstrates that the gel is made of supramolecular nanotubes: the high stability of the gel allows the determination from SAXS data of precise nanotube metrics such as diameter, helical pitch and monoclinic cell of the folded 2D crystal lattice along the tube direction. Additionally, static and dynamic magnetic investigations show the persistence of the SCM behavior in the metallogel. Last, on-surface gelation provides thick films as well as sub-monolayer deposits of supramolecular nanotubes on surface as evidenced by atomic force microscopy (AFM) observations. This paves the road toward magnetic materials and devices made of SCMs profiting of their isolation on surface as individual chains.