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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Forner-Cuenca, Antoni
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Effects of N-functional groups on the electron transfer kinetics of VO 2+ /VO 2 + at carbon:Decoupling morphology from chemical effects using model systemscitations
- 2024Elucidating the influence of electrolyte additives on iron electroplating performancecitations
- 2024Manufacturing Free-Standing, Porous Metallic Layers with Dynamic Hydrogen Bubble Templatingcitations
- 2023Investigating Mass Transfer Relationships in Stereolithography 3D Printed Electrodes for Redox Flow Batteriescitations
- 2023Surfactant doped polyaniline coatings for functionalized gas diffusion layers in low temperature fuel cellscitations
- 2023Engineering Lung-Inspired Flow Field Geometries for Electrochemical Flow Cells with Stereolithography 3D Printingcitations
- 2021Wire based electrospun composite short side chain perfluorosulfonic acid/polyvinylidene fluoride membranes for hydrogen-bromine flow batteriescitations
- 2020Ultrathin Conformal oCVD PEDOT Coatings on Carbon Electrodes Enable Improved Performance of Redox Flow Batteriescitations
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article
Surfactant doped polyaniline coatings for functionalized gas diffusion layers in low temperature fuel cells
Abstract
Gas diffusion layers (GDLs) are essential for the proper distribution of the reaction gases, the removal of excess water as well as electrical contact in polymer electrolyte fuel cells (PEFCs). The production of state-of-the-art GDLs consists of many steps such as graphitization at high temperatures and hydrophobic treatments with polytetrafluoroethylene (PTFE) which increase the cost. In this study, an electrically conductive and hydrophobic polyaniline (PANI) coating was deposited on carbon paper via dip-coating and electropolymerization to fabricate PTFE-free GDLs. As a proof-of-concept, PANI-coated GDLs were tested as a cathodic GDL in a single cell PEFC and achieved a 42% higher maximum power compared to the reference measurement with a commercial GDL. Furthermore, these PTFE-free GDLs achieved contact angles up to 144° which is in the range of commercial GDLs. The chemical composition of the PANI-coating was investigated via infrared spectroscopy and energy dispersive X-ray spectroscopy (EDX) and the morphology was examined via scanning electron microscopy (SEM). Hence, the proposed method emerges as a possible strategy to simultaneously substitute PTFE and apply a protective and durable coating.