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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Miola, Matteo
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Topics
Publications (10/10 displayed)
- 2023Nickel Boride (Ni x B) Nanocrystals:From Solid-State Synthesis to Highly Colloidally Stable Inkscitations
- 2023Nickel Boride (NixB) Nanocrystalscitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO 2 Reduction to Formatecitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective CO<sub>2</sub> Reduction to Formatecitations
- 2020Restructuring Metal–Organic Frameworks to Nanoscale Bismuth Electrocatalysts for Highly Active and Selective $CO_{2}$ Reduction to Formatecitations
- 2019Structural changes during water-mediated amorphization of semiconducting two-dimensional thiostannatescitations
- 2019Green Carbon-based Nanomaterials for CO2 Electroreduction
- 2019Increased Refractive Index Sensitivity by Circular Dichroism Sensing through Reduced Substrate Effectcitations
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article
All-dry, one-step synthesis, doping and film formation of conductive polypyrrole
Abstract
<p>Oxidative chemical vapor deposition (oCVD) is an extremely effective method for solvent-free deposition of highly conductive polypyrrole films, where polymer synthesis, doping, and film formation are combined in a single step. Here we show that by carefully tuning the reaction parameters, namely the deposition temperature, the reactor pressure and the oxidant to monomer flow rate ratio, homogeneous polypyrrole films with a record conductivity of 180 S cm-1 for a solvent-free method were produced. Fourier transform infrared spectroscopy, UV-vis spectrophotometry, X-ray photoelectron spectroscopy, scanning electron microscopy, and four-probe surface resistivity measurements were performed to gain insights into the relationship between different reaction conditions and the structure of oCVD-deposited polypyrrole, the development of defects, the film morphology and its physical properties.</p>