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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Luxenhofer, Robert
University of Helsinki
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2025Amorphous solid dispersions of amphiphilic polymer excipients and indomethacin prepared by hot melt extrusioncitations
- 2024Amorphous solid dispersions of amphiphilic polymer excipients and indomethacin prepared by hot melt extrusioncitations
- 2024Perfusable Tissue Bioprinted into a 3D-Printed Tailored Bioreactor Systemcitations
- 2023Investigation of cationic ring-opening polymerization of 2-oxazolines in the "green" solvent dihydrolevoglucosenonecitations
- 2021Poly(2-ethyl-2-oxazoline-co-N-propylethylene imine)s by controlled partial reduction of poly(2-ethyl-2-oxazoline)citations
- 2021From Thermogelling Hydrogels toward Functional Bioinkscitations
- 2021Melt electrowriting of poly(vinylidene difluoride) using a heated collectorcitations
- 2021Probing the Complex Loading-Dependent Structural Changes in Ultrahigh Drug-Loaded Polymer Micelles by Small-Angle Neutron Scatteringcitations
- 2021Poly(2-ethyl-2-oxazoline-co-N-propylethylene imine)s by controlled partial reduction of poly(2-ethyl-2-oxazoline) : synthesis, characterization and cytotoxicitycitations
- 2021Inverse Thermogelation of Aqueous Triblock Copolymer Solutions into Macroporous Shear-Thinning 3D Printable Inkscitations
- 2021From Thermogelling Hydrogels toward Functional Bioinks : Controlled Modification and Cytocompatible Crosslinkingcitations
- 2021Poly(2-ethyl-2-oxazoline-co-N-propylethylene imine)s by controlled partial reduction of poly(2-ethyl-2-oxazoline): synthesis, characterization and cytotoxicitycitations
- 2021Think Beyond the Core : Impact of the Hydrophilic Corona on Drug Solubilization Using Polymer Micellescitations
- 2021Freeform direct laser writing of versatile topological 3D scaffolds enabled by intrinsic support hydrogelcitations
- 2021Poly(2-ethyl-2-oxazoline-co-N -propylethylene imine)s by controlled partial reduction of poly(2-ethyl-2-oxazoline): Synthesis, characterization and cytotoxicitycitations
- 2021Development of a 3D printable and highly stretchable ternary organic–inorganic nanocomposite hydrogelcitations
- 2020Think Beyond the Corecitations
- 2020Probing the Complex Loading-Dependent Structural Changes in Ultrahigh Drug-Loaded Polymer Micelles by Small-Angle Neutron Scatteringcitations
- 2020Probing the Complex Loading-Dependent Structural Changes in Ultrahigh Drug-Loaded Polymer Micelles by Small-Angle Neutron Scatteringcitations
- 2019Silanization of silica nanoparticles and their processing as nanostructured micro-raspberry powders - a route to control the mechanical properties of isoprene rubber compositescitations
- 2018Colloidal core-satellite supraparticles via preprogramed burst of nanostructured micro-raspberry particlescitations
- 2017Burstable nanostructured micro-raspberries: Towards redispersible nanoparticles from dry powderscitations
- 2011Structure-property relationship in cytotoxicity and cell uptake of poly(2-oxazoline) amphiphilescitations
Places of action
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article
Development of a 3D printable and highly stretchable ternary organic–inorganic nanocomposite hydrogel
Abstract
Hydrogels that can be processed with additive manufacturing techniques and concomitantly possess favorable mechanical properties are interesting for many advanced applications. However, the development of novel ink materials with high intrinsic 3D printing performance has been proven to be a major challenge. Herein, a novel 3D printable organic–inorganic hybrid hydrogel is developed from three components, and characterized in detail in terms of rheological property, swelling behavior and composition. The nanocomposite hydrogel combines a thermoresponsive hydrogel with clay LAPONITE® XLG and in situ polymerized poly(N,N-dimethylacrylamide). Before in situ polymerization, the thermogelling and shear thinning properties of the thermoresponsive hydrogel provides a system well-suited for extrusion-based 3D printing. After chemical curing of the 3D-printed constructs by free radical polymerization, the resulting interpenetrating polymer network hydrogel shows excellent mechanical strength with a high stretchability to a tensile strain at break exceeding 550%. Integrating with the advanced 3D-printing technique, the introduced material could be interesting for a wide range of applications including tissue engineering, drug delivery, soft robotics and additive manufacturing in general.