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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Tan, Jeannie Z. Y.
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Publications (5/5 displayed)
- 2024From brew to clean fuelcitations
- 2022Production of CH4 and CO on CuxO and NixOy coatings through CO2 photoreductioncitations
- 2022Core-shell TiO2-x-CuyO microspheres for photogeneration of cyclic carbonates under simulated sunlightcitations
- 2021Comparative study of CO2 photoreduction using different conformations of CuO photocatalystcitations
- 2019Photo-generation of cyclic carbonates using hyper-branched Ru-TiO2citations
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article
Core-shell TiO2-x-CuyO microspheres for photogeneration of cyclic carbonates under simulated sunlight
Abstract
<p>Propylene carbonates are important organic solvents and feedstocks for different applications, including synthesis of polymers and Li-batteries. The generation of propylene carbonate utilising anthropogenic CO<sub>2</sub> and renewable solar energy offers an alternative sustainable process with a closed loop carbon cycle. The development of microstructured photocatalysts with desired properties, including high degree of product selectivity, wide range of optical properties, and maximised conversion yield, plays an important role for effective production of propylene carbonate from CO<sub>2</sub>. A hierachical hollow core with a double shell of TiO<sub>2-x</sub>-Cu<sub>2</sub>O-CuO was fabricated using the versatile solvothermal-microwave synthesis method. The fabricated sample revealed effective cascading of photogenerated electrons and holes that promoted the conversion of propylene carbonate (i.e., 1.6 wt%) under 1 Sun irradiation.</p>