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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Divitini, Giorgio
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (37/37 displayed)
- 2024Decoupled High‐Mobility Graphene on Cu(111)/Sapphire via Chemical Vapor Depositioncitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Heterostructures via a Solution‐Based Anion Exchange in Microcrystalline 2D Layered Metal‐Halide Perovskitescitations
- 2024Dry synthesis of bi-layer nanoporous metal films as plasmonic metamaterialcitations
- 2023Photogeneration of spin quintet triplet–triplet excitations in DNA-assembled pentacene stackscitations
- 2023Photogeneration of Spin Quintet Triplet–Triplet Excitations in DNA-Assembled Pentacene Stacks
- 2023Photogeneration of Spin Quintet Triplet-Triplet Excitations in DNA-Assembled Pentacene Stacks.
- 2022One Hundred-Nanometer-Sized CsPbBr3/m-SiO2 Composites Prepared via Molten-Salts Synthesis are Optimal Green Phosphors for LCD Display Devicescitations
- 2022Sol-gel processing of a covalent organic framework for the generation of hierarchically porous monolithic adsorbentscitations
- 2022Sodium Diffuses from Glass Substrates through P1 Lines and Passivates Defects in Perovskite Solar Modules
- 2021Beyond 17% stable perovskite solar module via polaron arrangement of tuned polymeric hole transport layercitations
- 2021Using pulsed mode scanning electron microscopy for cathodoluminescence studies on hybrid perovskite films
- 2021Using pulsed mode scanning electron microscopy for cathodoluminescence studies on hybrid perovskite films
- 2021Stepwise collapse of a giant pore metal-organic frameworkcitations
- 2021Mixed hierarchical local structure in a disordered metal–organic frameworkcitations
- 2021Nanometric Chemical Analysis of Beam-Sensitive Materials: A Case Study of STEM-EDX on Perovskite Solar Cells.
- 2020Colloidal Synthesis and Optical Properties of Perovskite-Inspired Cesium Zirconium Halide Nanocrystals.
- 2020Performance-limiting nanoscale trap clusters at grain junctions in halide perovskites.
- 2020Pair suppression caused by mosaic-twist defects in superconducting Sr2RuO4 thin-films prepared using pulsed laser depositioncitations
- 2020Ion Migration‐Induced Amorphization and Phase Segregation as a Degradation Mechanism in Planar Perovskite Solar Cells
- 2019High throughput production of single-wall carbon nanotube fibres independent of sulfur-source.
- 2019High throughput production of single-wall carbon nanotube fibres independent of sulfur-source.
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivationcitations
- 2018Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
- 2018Potassium- and Rubidium-Passivated Alloyed Perovskite Films: Optoelectronic Properties and Moisture Stability.
- 2018Core-Shell Electrospun Polycrystalline ZnO Nanofibers for Ultra-Sensitive NO2 Gas Sensing.
- 2018Dedoping of Lead Halide Perovskites Incorporating Monovalent Cations.
- 2018Exciton-Phonon Interactions Govern Charge-Transfer-State Dynamics in CdSe/CdTe Two-Dimensional Colloidal Heterostructures.
- 2017Tuning the properties of a black TiO<sub>2</sub>-Ag visible light photocatalyst produced by rapid one-pot chemical reductioncitations
- 2017Tuning the properties of a black TiO 2 -Ag visible light photocatalyst produced by rapid one-pot chemical reduction
- 2017Chemical vapour deposition of freestanding sub-60 nm graphene gyroidscitations
- 2016In Situ Heat-Induced Replacement of GaAs Nanowires by Au.
- 2015Interface and Composition Analysis on Perovskite Solar Cells.
- 2015Interface and Composition Analysis on Perovskite Solar Cellscitations
- 2015Local Versus Long-Range Diffusion Effects of Photoexcited States on Radiative Recombination in Organic-Inorganic Lead Halide Perovskites.
- 2011Flexible and biocompatible microelectrode arrays fabricated by supersonic cluster beam deposition on SU-8citations
Places of action
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article
Stepwise collapse of a giant pore metal-organic framework
Abstract
<p>Defect engineering is a powerful tool that can be used to tailor the properties of metal-organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show that milling leads to the breaking of metal-linker bonds, generating additional coordinatively unsaturated metal sites, and ultimately causes amorphisation. Pair distribution function analysis shows the hierarchical local structure is partially retained, even in the amorphised material. We find that solvents can be used to stabilise the MIL-100 (Fe) framework against collapse, which leads to a substantial retention of porosity over the non-stabilised material.</p>