| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Sapnik, Af
University of Copenhagen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Transient intermediate in the formation of an amorphous metal-organic frameworkcitations
- 2023Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glasscitations
- 2023Mapping nanocrystalline disorder within an amorphous metal–organic frameworkcitations
- 2023Structural insights into hybrid immiscible blends of metal–organic framework and sodium ultraphosphate glassescitations
- 2022Modeling the Effect of Defects and Disorder in Amorphous Metal-Organic Frameworkscitations
- 2021Melting of hybrid organic–inorganic perovskitescitations
- 2021Stepwise collapse of a giant pore metal-organic frameworkcitations
- 2021Mixed hierarchical local structure in a disordered metal–organic frameworkcitations
- 2020A new route to porous metal-organic framework crystal-glass compositescitations
- 2018Compositional inhomogeneity and tuneable thermal expansion in mixed-metal ZIF-8 analoguescitations
- 2018Uniaxial negative thermal expansion and metallophilicity in Cu3[Co(CN)6]citations
Places of action
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article
Stepwise collapse of a giant pore metal-organic framework
Abstract
<p>Defect engineering is a powerful tool that can be used to tailor the properties of metal-organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show that milling leads to the breaking of metal-linker bonds, generating additional coordinatively unsaturated metal sites, and ultimately causes amorphisation. Pair distribution function analysis shows the hierarchical local structure is partially retained, even in the amorphised material. We find that solvents can be used to stabilise the MIL-100 (Fe) framework against collapse, which leads to a substantial retention of porosity over the non-stabilised material.</p>