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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hecksher, Tina
Roskilde University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024RUSC (Roskilde University Shear Code)
- 2022Piezoelectric shear rheometrycitations
- 2022Rheological model for the alpha relaxation of glass-forming liquids and its comparison to data for DC704 and DC705citations
- 2021Identity of the local and macroscopic dynamic elastic responses in supercooled 1-propanolcitations
- 2019Fast contribution to the activation energy of a glass-forming liquidcitations
- 2017Model for the alpha and beta shear-mechanical properties of supercooled liquids and its comparison to squalane datacitations
- 2017Connection between fragility, mean-squared displacement and shear modulus in two van der Waals bonded glass-forming liquidscitations
- 2016Communicationcitations
- 2015Communication: Direct tests of single-parameter agingcitations
- 2015A review of experiments testing the shoving modelcitations
- 2014The dynamic bulk modulus of three glass-forming liquidscitations
- 2013Mechanical spectra of glass-forming liquids. I. Low-frequency bulk and shear moduli of DC704 and 5-PPE measured by piezoceramic transducerscitations
- 2013Mechanical spectra of glass-forming liquids. II. Gigahertz-frequency longitudinal and shear acoustic dynamics in glycerol and DC704 studied by time-domain Brillouin scatteringcitations
Places of action
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article
Identity of the local and macroscopic dynamic elastic responses in supercooled 1-propanol
Abstract
Glass-forming liquids are well known to have significant dynamic heterogeneities, leading to spatially grossly varying elastic properties throughout the system. In this paper, we compare the local elastic response of supercooled 1-propanol monitored by triplet state solvation dynamics to the macroscopic dynamic shear modulus measured by a piezo-electric gauge. The time-dependent responses are found to be identical, which means that the dynamic macroscopic shear modulus provides a good measure of the average local elastic properties. Since the macroscopic shear modulus of a dynamically inhomogeneous system in general is not just the average of the local moduli, there was no reason to expect such a result. This surprising finding not only provides constraints for models of dynamical heterogeneities in glass-forming liquids, but also allows for a fairly straightforward check on elastic models for glassy dynamics. This journal is