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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Richards, Bryce S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2022Unclonable Anti-Counterfeiting Labels Based on Microlens Arrays and Luminescent Microparticlescitations
- 2021Solar Pumping of Fiber Lasers with Solid-State Luminescent Concentrators: Design Optimization by Ray Tracingcitations
- 2021Upscaling of perovskite solar modules: The synergy of fully evaporated layer fabrication and all‐laser‐scribed interconnections
- 2021Interface Pattern Engineering in Core-Shell Upconverting Nanocrystals: Shedding Light on Critical Parameters and Consequences for the Photoluminescence Properties
- 2021Exciton versus free carrier emission: Implications for photoluminescence efficiency and amplified spontaneous emission thresholds in quasi-2D and 3D perovskitescitations
- 2021Interface Pattern Engineering in Core‐Shell Upconverting Nanocrystals: Shedding Light on Critical Parameters and Consequences for the Photoluminescence Propertiescitations
- 2020Correction: Guest-responsive polaritons in a porous framework: chromophoric sponges in optical QED cavitiescitations
- 2020A fully planar solar pumped laser based on a luminescent solar collector
- 2020Inkjet‐Printed Micrometer‐Thick Perovskite Solar Cells with Large Columnar Grains
- 2020Guest-responsive polaritons in a porous framework: chromophoric sponges in optical QED cavitiescitations
- 2020Chemical vapor deposited polymer layer for efficient passivation of planar perovskite solar cellscitations
- 2019Continuous wave amplified spontaneous emission in phase-stable lead halide perovskitescitations
- 2019Vacuum‐Assisted Growth of Low‐Bandgap Thin Films (FA$_{0.8}$MA$_{0.2}$Sn$_{0.5}$Pb$_{0.5}$I$_{3}$) for All‐Perovskite Tandem Solar Cellscitations
- 2019Continuous wave amplified spontaneous emission in phase-stable triple cation lead halide perovskite thin filmscitations
- 2019Inkjet‐Printed Micrometer‐Thick Perovskite Solar Cells with Large Columnar Grainscitations
- 2018Inkjet-Printed Photoluminescent Patterns of Aggregation-Induced-Emission Chromophores on Surface-Anchored Metal–Organic Frameworkscitations
- 2018Reaction of porphyrin-based surface-anchored metal-organic frameworks to prolonged illumination
- 2018Reaction of porphyrin-based surface-anchored metal–organic frameworks caused by prolonged illumination
- 2017Triple cation mixed-halide perovskites for tunable lasers
- 2017Facile loading of thin-film surface-anchored metal-organic frameworks with Lewis-base guest moleculescitations
- 2017Facile loading of thin-film surface-anchored metal-organic frameworks with Lewis-base guest moleculescitations
- 2014Luminescent Polymer Films from Simple Processing of Coronene and Europium Precursors in Watercitations
- 2013Enhanced up-conversion for photovoltaics using 2D photonic crystalscitations
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article
Chemical vapor deposited polymer layer for efficient passivation of planar perovskite solar cells
Abstract
Reducing non-radiative recombination losses by advanced passivation strategies is pivotal to maximize the power conversion efficiency (PCE) of perovskite solar cells (PSCs). Previously, polymers such as poly(methyl methacrylate), poly(ethylene oxide), and polystyrene were successfully applied in solution-processed passivation layers. However, controlling the thickness and homogeneity of these ultra-thin passivation layers on top of polycrystalline perovskite thin films is a major challenge. In response to this challenge, this work reports on chemical vapor deposition (CVD) polymerization of poly(p-xylylene) (PPX) layers at controlled substrate temperatures (14–16 °C) for efficient surface passivation of perovskite thin films. Prototype double-cation PSCs using a ∼1 nm PPX passivation layer exhibit an increase in open-circuit voltage (V$_{OC}$) of ∼40 mV along with an enhanced fill factor (FF) compared to a non-passivated PSC. These improvements result in a substantially enhanced PCE of 20.4% compared to 19.4% for the non-passivated PSC. Moreover, the power output measurements over 30 days under ambient atmosphere (relative humidity ∼40–50%) confirm that the passivated PSCs are more resilient towards humidity-induced degradation. Considering the urge to develop reliable, scalable and homogeneous deposition techniques for future large-area perovskite solar modules, this work establishes CVD polymerization as a novel approach for the passivation of perovskite thin films.