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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Baranov, Dmitry
Lund University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2024Exogenous Metal Cations in the Synthesis of CsPbBr3 Nanocrystals and Their Interplay with Tertiary Aminescitations
- 2023Collective Diffraction Effects in Perovskite Nanocrystal Superlatticescitations
- 2022Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core-Shell Nanocrystalscitations
- 2022Highly Emitting Perovskite Nanocrystals with 2-Year Stability in Water through an Automated Polymer Encapsulation for Bioimagingcitations
- 2021Detection of Pb2+traces in dispersion of Cs4PbBr6 nanocrystals by in situ liquid cell transmission electron microscopycitations
- 2021Structure and Surface Passivation of Ultrathin Cesium Lead Halide Nanoplatelets Revealed by Multilayer Diffractioncitations
- 2021Metamorphoses of Cesium Lead Halide Nanocrystalscitations
- 2021Exploiting the Transformative Features of Metal Halides for the Synthesis of CsPbBr3@SiO2 Core–Shell Nanocrystalscitations
- 2020Superlattices are greener on the other sidecitations
- 2020Transforming colloidal Cs4PbBr6 nanocrystals with poly(maleic anhydride-alt-1-octadecene) into stable CsPbBr3 perovskite emitters through intermediate heterostructurescitations
- 2020Cs 3 Cu 4 In 2 Cl 13 Nanocrystals:A Perovskite-Related Structure with Inorganic Clusters at A Sitescitations
- 2020Cs3Cu4In2Cl13 Nanocrystalscitations
- 2019Purification of Oleylamine for Materials Synthesis and Spectroscopic Diagnostics for trans Isomerscitations
- 2019Fully Inorganic Ruddlesden-Popper Double Cl-I and Triple Cl-Br-I Lead Halide Perovskite Nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2018Colloidal Synthesis of Double Perovskite Cs2AgInCl6 and Mn-Doped Cs2AgInCl6 Nanocrystalscitations
- 2007Synthesis of cerium oxide nanoparticles in polyethylene matrixcitations
- 2006Optical properties of cadmium sulfide nanoparticles on the surface of polytetrafluoroethylene nanogranulescitations
- 2006Cobalt-containing core-shell nanoparticles on the surface of poly(tetrafluoroethylene) microgranulescitations
- 2006Copper nanoparticles on the surface of ultradispersed polytetrafluoroethylene nanograinscitations
- 2006New magnetic materials based on cobalt and iron-containing nanopariclescitations
- 2005Synthesis and structure of polyethylene-matrix composites containing zinc oxide nanoparticlescitations
Places of action
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article
Transforming colloidal Cs4PbBr6 nanocrystals with poly(maleic anhydride-alt-1-octadecene) into stable CsPbBr3 perovskite emitters through intermediate heterostructures
Abstract
<p>The preparation of strongly emissive CsPbBr<sub>3</sub> perovskite nanocrystals with robust surface passivation is a challenge in the field of lead halide perovskite nanomaterials. We report an approach to prepare polymer-capped CsPbBr<sub>3</sub> perovskite nanocrystals by reacting oleylammonium/oleate-capped Cs<sub>4</sub>PbBr<sub>6</sub> nanocrystals with poly(maleic anhydride-alt-1-octadecene) (PMAO). PMAO contains succinic anhydride units that are reactive towards the oleylamine species present on the Cs<sub>4</sub>PbBr<sub>6</sub> nanocrystals' surface and produces polysuccinamic acid, which, in turn, triggers the Cs<sub>4</sub>PbBr<sub>6</sub> to CsPbBr<sub>3</sub> conversion. The transformation occurs through the formation of Cs<sub>4</sub>PbBr<sub>6</sub>-CsPbBr<sub>3</sub> heterostructures as intermediates, which are captured because of the mild reactivity of PMAO and are investigated by high-resolution electron microscopy. The Cs<sub>4</sub>PbBr<sub>6</sub>-CsPbBr<sub>3</sub> heterostructures demonstrate a dual emission at cryogenic temperature with an indication of the energy transfer from Cs<sub>4</sub>PbBr<sub>6</sub> to CsPbBr<sub>3</sub>. The fully-transformed CsPbBr<sub>3</sub> NCs have high photoluminescence quantum yield and enhanced colloidal stability, which we attribute to the adhesion of polysuccinamic acid to the NC surface through its multiple functional groups in place of oleate and alkylammonium ligands. The PMAO-induced transformation of Cs<sub>4</sub>PbBr<sub>6</sub> NCs opens up a strategy for the chemical modification of metal halide NCs initially passivated with nucleophilic amines.</p>