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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bose, Suryasarathi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2022Distribution of Carbon Nanotubes in Polycarbonate-Based Blends for Electromagnetic Interference Shieldingcitations
- 2022The Mechanical, Dielectric, and EMI Shielding Properties of Nickel Ferrite (NiF)/Graphene (Gr)-Doped Epoxy Compositescitations
- 2021The journey of polycarbonate-based composites towards suppressing electromagnetic radiationcitations
- 2021Ultrathin structures derived from interfacially modified polymeric nanocomposites to curb electromagnetic pollutioncitations
- 2020Does the Type of Polymer and Carbon Nanotube Structure Control the Electromagnetic Shielding in Melt-Mixed Polymer Nanocomposites?citations
- 2019HDPE/UHMWPE hybrid nanocomposites with surface functionalized graphene oxide towards improved strength and cytocompatibilitycitations
- 2018Tailored distribution of nanoparticles in bi-phasic polymeric blends as emerging materials for suppressing electromagnetic radiation: challenges and prospectscitations
- 2018Does the Processing Method Resulting in Different States of an Interconnected Network of Multiwalled Carbon Nanotubes in Polymeric Blend Nanocomposites Affect EMI Shielding Properties?citations
- 2018PVDF–MWNT interactions control process induced β-lamellar morphology and orientation in the nanocompositescitations
- 2018Tuneable Dielectric Properties Derived from Nitrogen-Doped Carbon Nanotubes in PVDF-Based Nanocompositescitations
- 2017Graphene Derivatives Doped with Nickel Ferrite Nanoparticles as Excellent Microwave Absorbers in Soft Nanocompositescitations
- 2017Electromagnetic screening in soft conducting composite-containing ferrites: the key role of size and shape anisotropycitations
- 2017Graphene oxide co-doped with dielectric and magnetic phases as an electromagnetic wave suppressorcitations
- 2016Exceptional microwave absorption in soft polymeric nanocomposites facilitated by engineered nanostructurescitations
- 2016Construction of a carbon fiber based layer-by-layer (LbL) assembly – a smart approach towards effective EMI shieldingcitations
- 2016A strategy to achieve enhanced electromagnetic interference shielding at ultra-low concentration of multiwall carbon nanotubes in PaMSAN/PMMA blends in the presence of a random copolymer PS-r-PMMAcitations
- 2010Assessing the strengths and weaknesses of various types of pre-treatments of carbon nanotubes on the properties of polymer/carbon nanotubes composites: A critical review
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article
Ultrathin structures derived from interfacially modified polymeric nanocomposites to curb electromagnetic pollution
Abstract
The use of electronic devices and wireless networks is increasing rapidly, and electromagnetic (EM) pollution remediation remains a challenge. We employed a unique approach to fabricate two ultrathin (approx. 53 μm) multilayered assemblies to address this. By sequentially stacking thin films of polyvinylidene difluoride (PVDF) and polycarbonate (PC) nanocomposites and interfacially locking them with a mutually miscible polymer (PMMA, polymethyl methacrylate), materials with enhanced structural properties and electromagnetic interference (EMI) shielding performance can be designed. Utilizing reduced graphene oxide (rGO) and molybdenum disulfide (MoS2) as a template, ferrite was grown on the surface to design two different nanohybrid structures (rGO–Fe3O4 and MoS2–Fe3O4). PVDF was composited with either rGO–Fe3O4 or MoS2–Fe3O4, and multiwall carbon nanotubes (CNTs) were dispersed in the PC component. As PC and PVDF are immiscible, their poor interface would result in inferior structural properties, which can be challenging in designing EMI shielding materials due to cyclic thermal fatigue. Hence, PMMA is sandwiched to interfacially stitch the components (PC and PVDF) and improve interfacial adhesion. This was confirmed using SEM/EDS and Raman mapping/imaging. The mechanical stability of the multilayered assemblies was characterized using a dynamic mechanical analyzer (DMA), and the storage modulus was found to be as high as 2767 MPa at 40 °C (@constant frequency and strain amplitude), for the multilayered film with rGO–Fe3O4 in PVDF, PMMA as a sandwich layer and CNTs in PC. A typical assembly of 9 multilayers (∼480 μm) with rGO–Fe3O4 in PVDF, and CNTs in PC, and interfacially stitched with PMMA gave rise to a high EMI shield effectiveness (SET) of −26.3 dB @ 26.5 GHz. This unique arrangement of a multilayered assembly suppressed EMI primarily by absorption. ; publishedVersion