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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mariotti, Davide
University of Strathclyde
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Low temperature plasma‐assisted double anodic dissolution: a new approach for the synthesis of GdFeO3 perovskite nanoparticlescitations
- 2024Low temperature plasma‐assisted double anodic dissolution: a new approach for the synthesis of GdFeO 3 perovskite nanoparticlescitations
- 2024Stability in Photoluminescence and Photovoltaic Properties of Formamidinium Lead Iodide Quantum Dots
- 2023A Single‐Step Process to Produce Carbon Nanotube‐Zinc Compound Hybrid Materialscitations
- 2021Carrier extraction from metallic perovskite oxide nanoparticlescitations
- 2021Understanding plasma–ethanol non-equilibrium electrochemistry during the synthesis of metal oxide quantum dotscitations
- 2020Tuning the Bandgap Character of Quantum‐Confined Si–Sn Alloyed Nanocrystalscitations
- 2019Nanostructured perovskite solar cells
- 2018Zero-dimensional methylammonium iodo bismuthate solar cells and synergistic interactions with silicon nanocrystalscitations
- 2018Low-Loss and Tunable Localized Mid-Infrared Plasmons in Nanocrystals of Highly Degenerate InNcitations
- 2018Microplasma-assisted electrochemical synthesis of Co3O4 nanoparticles in absolute ethanol for energy applicationscitations
- 2017Zero-dimensional methylammonium iodo bismuthate solar cells and synergistic interactions with silicon nanocrystalscitations
- 2017Charge carrier localised in zero-dimensional (CH 3 NH 3 ) 3 Bi 2 1 9 clusterscitations
- 2017Charge carrier localised in zero-dimensional (CH3NH3)3Bi219 clusterscitations
- 2017Charge carrier localised in zero-dimensional (CH3NH3)3Bi219 clusterscitations
- 2017Charge carrier localised in zero-dimensional (CH3NH3)3Bi2I9 clusterscitations
- 2013Improved Optoelectronic Properties of Silicon Nanocrystals/Polymer Nanocomposites by Microplasma-Induced Liquid Chemistrycitations
Places of action
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article
Understanding plasma–ethanol non-equilibrium electrochemistry during the synthesis of metal oxide quantum dots
Abstract
Plasma–liquid interactions are becoming increasingly interesting due to their key features such as non-faradaic, non-equilibrium behaviour as well as electron-driven reactions, therefore with potential strong impact for several promising applications. However, understanding reaction mechanisms initiated at the plasma–liquid interface is complicated by short timescales and spatial non-uniformities. Here we study a plasma–ethanol system that has general relevance to broaden our understanding of plasma interacting at the surface of a liquid. This plasma-electrochemical approach has been successfully used to synthesize a range of metal–oxide nanoparticles and quantum dots (QDs). While nanoparticles and QDs can be an end to this process, they can also be viewed as ‘chemical probes’ that help understanding the underlying and progenitor chemical reactions. We have therefore studied plasma–ethanol interactions during the synthesis of CuO QDs. The colloid was characterised by Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, nuclear magnetic resonance spectroscopy and gas chromatography-mass spectrometry. Further, measurements for pH and other trace products were also carried out. The analysis shows the acidolysis of the ethanol electrolyte where hydrogen peroxide was found after the plasma process. A semi-quantification of Cu ions was carried out to confirm the anodic dissolution of the Cu metal foil. Thus, a detailed set of reactions are proposed and has been discussed in detail. Material characterisation relied on transmission electron microscopy and X-ray photoelectron spectroscopy which provided important and complementary information to corroborate chemical reaction paths.