| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cseri, Levente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronicscitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2020Metal–Organic Frameworks (MOFs) and MOF-Derived Porous Carbon Materials for Sustainable Adsorptive Wastewater Treatment
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Robust Covalently Crosslinked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Robust Covalently Cross-linked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
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article
Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalination
Abstract
This research reports the fabrication of nanocomposite cation exchange membranes (CEMs) by incorporating negatively charged graphene-based nanomaterials into a non-charged poly(vinylidene fluoride) (PVDF) matrix using a mold-casting technique developed in-house. Graphene oxide (GO) or reduced graphene oxide (rGO) nanosheets were modified into ion exchange group carriers using a sulfonic group-bearing agent based on poly(sodium 4-styrenesulfonate)/3,4-dihydroxy-L-phenylalanine (PSS/L-DOPA) (SGO or SrGO). Such modified nanosheets provide the ion exchange capabilities in SGO/PVDF and SrGO/PVDF nanocomposite CEMs, respectively. Both nanocomposite CEMs displayed lower linear swelling ratios which are good for membrane stability. This was due to the presence of the nanomaterials which acted as pore fillers and increased the stiffness of the nanocomposite membranes. The ion exchange capacity (IEC) and permselectivity of the SGO/PVDF_45 CEMs were slightly higher than the values for the SrGO/PVDF_45 CEM. It was found that the SrGO additive increased the area resistance of the nanocomposite CEM. However, SrGO/PVDF_45 CEM demonstrated a higher current efficiency (7.5% higher than SGO/PVDF_45), which could be attributed to the improved electronic conductivity of rGO. It was found that both nanocomposite CEMs performed well in electrodialysis experiments to achieve the substantial salt removal rates, although the energy consumption results of the novel nanocomposite CEMs were higher than the conventional polymeric CEM. The above research results have successfully demonstrated the concept of fabricating nanocomposite cation exchange membranes (CEMs) for electrodialysis applications by employing negatively charged graphene-based nanomaterials as ion exchange carriers.