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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wang, Qiong
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Topics
Publications (7/7 displayed)
- 2023Large grain size with reduced non-radiative recombination in potassium incorporated methylammonium-free perovskite solar cellscitations
- 2021Tuning halide perovskite energy levelscitations
- 2021Tuning halide perovskite energy levelscitations
- 2020Globular structure of the hypermineralized tissue in human femoral neckcitations
- 2020Tuning halide perovskite energy levelscitations
- 2020Reply to the “Comment on the publication ‘Ferroelectricity-free lead halide perovskites’ by Gomez ” by Colsmanncitations
- 2020Patterning of transparent polymers using high-throughput methods: Application in flexible perovskite solar cells with enhanced light trapping
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article
Tuning halide perovskite energy levels
Abstract
<p>The ability to control the energy levels in semiconductors is compelling for optoelectronic applications. In this study, we managed to tune the work function (WF) of halide perovskite semiconductors using self-assembled monolayers of small molecules to induce stable dipoles at the surface. The direction and intensity of the surface dipoles rely on specific molecule-to-surface interactions. Electron acceptor or donor molecules result in the positive or negative WF shifts up to several hundreds of meV. Our approach provides a versatile tool to control the WF of halide perovskite and adjust the energy level alignment at the interface with charge transport materials in perovskite-based optoelectronics. The impact on perovskite solar cells is reported and discussed in detail with the support of modelling. </p>