| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Quadrelli, Paolo
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Topics
Publications (6/6 displayed)
- 2023Role of Chain Length on (CnH2n+1NH3)2PbX4 (n=6, 8, 10, 12, 14, 16; X=Br and I) 2D Metal Halide Perovskites Physical Properties and Hydrophobicity
- 2021Experimental Strategy and Mechanistic View to Boost the Photocatalytic Activity of Cs3Bi2Br9 Lead‐Free Perovskite Derivative by g‐C3N4 Composite Engineeringcitations
- 2021Role of spacer cations and structural distortion in two-dimensional germanium halide perovskitescitations
- 2021g-C3N4/metal halide perovskite composites as photocatalysts for singlet oxygen generation processes for the preparation of various oxidized synthonscitations
- 2021Application of metal halide perovskites as photocatalysts in organic reactionscitations
- 2016High-pressure behavior of methylammonium lead iodide (MAPbI3) hybrid perovskitecitations
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article
g-C3N4/metal halide perovskite composites as photocatalysts for singlet oxygen generation processes for the preparation of various oxidized synthons
Abstract
g-C3N4/metal halide perovskite composites were prepared and used for the first time as photocatalysts for in situ 1O2 generation to perform hetero Diels–Alder, ene and oxidation reactions with suitable dienes and alkenes. The standardized methodology was made applicable to a variety of olefinic substrates. The scope of the method is finely illustrated and the reactions afforded desymmetrized hydroxy-ketone derivatives, unsaturated ketones and epoxides. Some limitations were also observed, especially in the case of the alkene oxidations, and poor chemoselectivity was somewhere observed in this work which is the first application of MHP-based composites for in situ 1O2 generation. The experimental protocol can be used as a platform to further expand the knowledge and applicability of MHPs to organic reactions, since perovskites offer a rich variety of tuning strategies which may be explored to improve reaction yields and selectivities.