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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Høj, Martin
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Zinc Based High Temperature Methanol Synthesis Catalysts Enabling Direct Synthesis of Olefins and Aromatics from CO2
- 2022Zinc Based High Temperature Methanol Synthesis Catalysts Enabling Direct Synthesis of Olefins and Aromatics from CO 2
- 2020Structural dynamics of an iron molybdate catalyst under redox cycling conditions studied with in situ multi edge XAS and XRDcitations
- 2019Modeling of the molybdenum loss in iron molybdate catalyst pellets for selective oxidation of methanol to formaldehydecitations
- 2019Catalytic Hydropyrolysis of Biomass using Molybdenum Sulfide Based Catalyst. Effect of Promoterscitations
- 2018Hydrogen assisted catalytic biomass pyrolysis for green fuels. Effect of cata-lyst in the fluid bed
- 2011Flame spray synthesis of CoMo/Al2O3 hydrotreating catalystscitations
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article
Structural dynamics of an iron molybdate catalyst under redox cycling conditions studied with in situ multi edge XAS and XRD
Abstract
The structural dynamics and phase transformations of an iron molybdate catalyst with excess molybdenum trioxide (Mo/Fe = 2.0) were studied during redox cycling of the catalyst using in situ multi-edge X-ray absorption spectroscopy (XAS) at the Mo K-edge (transmission mode) and Fe K-edge (fluorescence mode) in combination with X-ray diffraction (XRD). X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) analysis showed that heating under reducing conditions with methanol up to 400 °C produced MoO<sub>2</sub> and FeMoO<sub>4</sub>. Linear combination fitting (LCF) analysis showed that iron was reduced completely, while molybdenum remained partly oxidized (60% as Mo(vi)). Complementary in situ XRD also supported the phase transformation due to reduction of Fe<sub>2</sub>(MoO<sub>4</sub>)<sub>3</sub> and MoO<sub>3 </sub>to FeMoO<sub>4</sub> and MoO<sub>2</sub>. Subsequent heating under oxidative conditions from 200 to 500 °C transformed the catalyst into its initial state via Fe<sub>2</sub>O<sub>3</sub> and extra MoO<sub>3</sub> as intermediate phases. This underlines the segregation and iron enrichment during redox cycling. MoO<sub>3</sub> volatilization, observed under industrial reaction conditions of a methanol and oxygen containing atmosphere, causes this segregation to be permanent. Complete regeneration could only be achieved at 500 °C, which is significantly higher than industrial reaction temperatures. Overall, multi edge in situ XAS along with complementary XRD was found to be an ideal tool for tracing the different amorphous and crystalline phases present during redox cycling of the catalyst.