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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Eslava, Salvador
Imperial College London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Activating 2D MoS2 by loading 2D Cu–S nanoplatelets for improved visible light photocatalytic hydrogen evolution, drug degradation, and CO2 reductioncitations
- 2024Ca‐doped PrFeO<sub>3</sub> photocathodes with enhanced photoelectrochemical activitycitations
- 2021Structural Evolution of Iron Forming Iron Oxide in a Deep Eutectic-Solvothermal Reactioncitations
- 2021Silver-Decorated TiO2 Inverse Opal Structure for Visible Light-Induced Photocatalytic Degradation of Organic Pollutants and Hydrogen Evolutioncitations
- 2020Silver-Decorated TiO2 Inverse Opal Structure for Visible Light-Induced Photocatalytic Degradation of Organic Pollutants and Hydrogen Evolutioncitations
- 2020Strategies for the deposition of LaFeO3 photocathodescitations
- 2019Graphite-protected CsPbBr3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in watercitations
- 2019Enhanced Ceria Nanoflakes using Graphene Oxide as a Sacrificial Template for CO Oxidation and Dry Reforming of Methanecitations
- 2019Inexpensive Metal Free Encapsulation Layers Enable Halide Perovskite Based Photoanodes for Water Splitting
- 2019Enhanced ceria nanoflakes using graphene oxide as a sacrificial template for CO oxidation and dry reforming of methanecitations
- 2019Enhanced ceria nanoflakes using graphene oxide as a sacrificial template for CO oxidation and dry reforming of methanecitations
- 2019Strategies for the deposition of LaFeO3 photocathodes:improving the photocurrent with a polymer templatecitations
- 2018Screen printed carbon CsPbBr3 solar cells with high open-circuit photovoltagecitations
- 2018Enhanced Ceria Nanoflakes using Graphene Oxide as a Sacrificial Template for CO Oxidation and Dry Reforming of Methanecitations
- 2018Efficient hematite photoanodes prepared by hydrochloric acid-treated solutions with amphiphilic graft copolymercitations
- 2017A facile way to produce epoxy nanocomposites having excellent thermal conductivity with low contents of reduced graphene oxidecitations
- 2016Autonomous self-healing structural composites with bio-inspired designcitations
- 2015Printing in Three Dimensions with Graphenecitations
- 2013Metal-organic framework ZIF-8 films as low-κ dielectrics in microelectronicscitations
- 2008Reaction of trimethylchlorosilane in spin-on Silicalite-1 zeolite filmcitations
- 2008Nanoporous organosilicate films prepared in acidic conditions using tetraalkylammonium bromide porogenscitations
- 2007Characterization of a molecular sieve coating using ellipsometric porosimetrycitations
- 2007Profile control of novel non-Si gates using B Cl3 N2 plasmacitations
Places of action
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article
Strategies for the deposition of LaFeO3 photocathodes
Abstract
<p>Renewable and sustainable alternatives to fossil fuels are needed to limit the impact of global warming. Using metal oxide semiconductors as photoelectrodes within photoelectrochemical cell devices, in which solar energy can be stored and ultimately used for electricity generation, is one such alternative. LaFeO<sub>3</sub> (LFO) has been shown to be an active photocathode in the illumination of visible light but is restricted by a low surface area and relatively low photocurrents achieved. The work herein utilizes a spin coating deposition method with a solution of nitrate precursors combined with a non-ionic polymeric surfactant (Triton X-100). This allowed for the formation of a uniform porous LFO film of high coverage on a fluorine-doped tin oxide-coated substrate by directing the growth and preventing particle aggregation during film fabrication. These porous LFO films achieved an enhanced photocurrent of -161 ± 6 μA cm<sup>-2</sup> at +0.43 V<sub>RHE</sub>, in addition to a remarkably high onset potential of +1.4 V<sub>RHE</sub> for cathodic photocurrent. It was additionally shown that the attained film quality and activity were superior to those of other film fabrication methods such as doctor blading and spray pyrolysis. With this polymer templating method for LFO films, not only are higher photocurrents achieved but there are also added benefits such as better charge separation, higher efficiencies, higher specific electrochemically active surface area, and improved stability.</p>