| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Martir, Diego Rota
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (2/2 displayed)
Places of action
| Organizations | Location | People |
|---|
article
A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units
Abstract
[2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, <b>pCpd3py</b> and <b>pCpd4py</b>, composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of <b>pCpd4py</b> with Pd<sup>2+</sup> metal ions afforded a [Pd<sub>3</sub>(<b>pCpd4py</b>)6]<sup>6+</sup> cage structure, <b>pCpd4py-Pd</b>, where the six <b>pCpd4py</b> ligands doubly bridge each edge of the Pd<sub>3</sub> triangular core. The ligand <b>pCpd4py</b> and the palladium cage <b>pCpd4py-Pd</b> have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations.