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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zysman-Colman, Eli
University of St Andrews
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2024Organic light-emitting diodes comprising an undoped thermally activated delayed fluorescence emissive layer and a thick inorganic perovskite hole transport layer
- 2024Organic Light-Emitting Diodes Comprising an Undoped Thermally Activated Delayed Fluorescence Emissive Layer and a Thick Inorganic Perovskite Hole Transport Layer
- 2021A luminescent 1D silver polymer containing [2.2]paracyclophane ligandscitations
- 2020A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane unitscitations
- 2020Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2020A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitscitations
- 2020What controls the orientation of TADF emitters?citations
- 2019A Pd 3 L 6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitscitations
- 2019Stable 6H organic-inorganic hybrid lead perovskite and competitive formation of 6H and 3C perovskite structure with mixed A cationscitations
- 2019A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Unitscitations
- 2017Lessons learned in tuning the optoelectronic properties of phosphorescent iridium(III) complexescitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups:a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groups : a combined experimental and theoretical studycitations
- 2017Blue-to-green emitting neutral Ir(III) complexes bearing pentafluorosulfanyl groupscitations
- 2016Synthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine ligandcitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(III) complexes bearing bisphosphine ligandscitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2016Synthesis, properties and Light-Emitting Electrochemical Cell (LEEC) device fabrication of cationic Ir(III) complexes bearing electron-withdrawing groups on the cyclometallating ligandscitations
- 2015Strategic modulation of the photonic properties of conjugated organometallic Pt–Ir polymers exhibiting hybrid CT-excited statescitations
- 2014Strategic modulation of the photonic properties of conjugated organometallic Pt–Ir polymers exhibiting hybrid CT-excited statescitations
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article
A Pd3L6 supramolecular cage incorporating photoactive [2.2]paracyclophane Units
Abstract
[2.2]Paracyclophane (pCp) scaffolds, unlike many -conjugated building blocks, have been rarely explored in supramolecular self-assembly. Herein we report the synthesis and characterization of two ligands, <b>pCpd3py</b> and <b>pCpd4py</b>, composed of a pCp core functionalized at its 7- and 15-positions respectively with 3-pyridyl and 4-pyridyl units. The self-assembly of <b>pCpd4py</b> with Pd<sup>2+</sup> metal ions afforded a [Pd<sub>3</sub>(<b>pCpd4py</b>)6]<sup>6+</sup> cage structure, <b>pCpd4py-Pd</b>, where the six <b>pCpd4py</b> ligands doubly bridge each edge of the Pd<sub>3</sub> triangular core. The ligand <b>pCpd4py</b> and the palladium cage <b>pCpd4py-Pd</b> have been characterized by NMR spectroscopy, ESI-MS spectrometry and X-ray diffraction analyses and their photophysical properties investigated by steady-state and time-resolved emission spectroscopy as well as Time-Dependent Density Functional Theory calculations.