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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Delerue Matos, C.
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Topics
Publications (8/8 displayed)
- 2022p A simple electrochemical detection of atorvastatin based on disposable screen-printed carbon electrodes modified by molecularly imprinted polymer: Experiment and simulationcitations
- 2020Azithromycin electrochemical detection using a molecularly imprinted polymer prepared on a disposable screen-printed electrodecitations
- 2019Electrochemical sensing of the thyroid hormone thyronamine (T(0)AM) via molecular imprinted polymers (MIPs)citations
- 2019Development of a disposable paper-based potentiometric immunosensor for real-time detection of a foodborne pathogencitations
- 2018Electrochemical genoassays on gold-coated magnetic nanoparticles to quantify genetically modified organisms (GMOs) in food and feed as GMO percentagecitations
- 2017PMo11V@N-CNT electrochemical properties and its application as electrochemical sensor for determination of acetaminophencitations
- 2014Sensitive bi-enzymatic biosensor based on polyphenoloxidases-gold nanoparticles-chitosan hybrid film-graphene doped carbon paste electrode for carbamates detectioncitations
- 2013Biosensor based on multi-walled carbon nanotubes paste electrode modified with laccase for pirimicarb pesticide quantificationcitations
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article
Azithromycin electrochemical detection using a molecularly imprinted polymer prepared on a disposable screen-printed electrode
Abstract
Azithromycin (AZY) is among the antibiotics with the highest concentrations in aqueous matrices. Conventional wastewater treatment plants (WWTPs) do not fully remove this compound and it has been found in the environment. The health effects of AZY on humans and the environment are not yet understood. Therefore, the development of sensitive and selective analytical methods for AZY determination is important. In this work, an electrochemical molecularly imprinted polymer (MIP) sensor was developed for the quantification of AZY. The selection of the functional monomer was performed by molecular modelling using quantum mechanics calculations. The MIP was electropolymerized by cyclic voltammetry (CV) on a screen-printed carbon electrode (SPCE) using a solution containing 4-aminobenzoic acid (4-ABA) in the presence of AZY as a template molecule. The characterisation of the sensor was carried out using scanning electron microscopy (SEM), CV and electrochemical impedance spectroscopy (EIS). The analysis of AZY was performed by differential pulse voltammetry (DPV) in the linear range between 0.5 and 10.0 mu M, with a limit of detection (LOD) of 0.08 mu M (S/N = 3) and a limit of quantification (LOQ) of 0.3 mu M (S/N = 10). The MIP sensor was found to have selectivity to recognise AZY molecules and was successfully applied in the analysis of tap water and water samples collected upstream of a WWTP output in the Ave River. The proposed sensor presents a simple, selective and environmentally friendly strategy for AZY determination in environmental water.