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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Budd, Peter M.
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Mixed matrix and thin-film nanocomposite membranes of PIM-1 and hydrolyzed PIM-1 with Ni- and Co-MOF-74 nanoparticles for CO2 separation: Comparison of blending, grafting and crosslinking fabrication methodscitations
- 2024Stiffening and softening of freshly prepared and aged CTA, PTMSP, and PIM‐1 films exposed to volatile compounds
- 2024High gas permeability in aged superglassy membranes with nanosized UiO-66−NH2/cPIM-1 network fillerscitations
- 2023CO2 separation using thin film composite membranes of acid-hydrolyzed PIM-1citations
- 2022Porous silica nanosheets in PIM-1 membranes for CO2 separationcitations
- 2022Thin film nanocomposite membranes of PIM-1 and graphene oxide/ZIF-8 nanohybrids for organophilic pervaporationcitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021PIM-1/Holey Graphene Oxide Mixed Matrix Membranes for Gas Separation: Unveiling the Role of Holescitations
- 2020Superglassy Polymers to Treat Natural Gas by Hybrid Membrane/Amine Processes: Can Fillers Help?citations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Impeded physical aging in PIM-1 membranes containing graphene-like fillerscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Ultrahigh-permeance PIM-1 based thin film nanocomposite membranes on PAN supports for CO 2 separationcitations
- 2018Ultrahigh-permeance PIM-1 based thin film nanocomposite membranes on PAN supports for CO2 separationcitations
- 2018Graphene/Polyamide Laminates for Supercritical CO 2 and H 2 S Barrier Applications: An Approach toward Permeation Shutdowncitations
- 2018Graphene/Polyamide Laminates for Supercritical CO2 and H2S Barrier Applications: An Approach toward Permeation Shutdowncitations
- 2017Enhanced organophilic separations with mixed matrix membranes of polymers of intrinsic microporosity and graphene-like fillerscitations
- 2016Synthesis and characterization of composite membranes made of graphene and polymers of intrinsic microporositycitations
- 2005Polymerization and carbonization of high internal phase emulsionscitations
- 2004Polymers of intrinsic microporosity (PIMs): Robust, solution-processable, organic nanoporous materialscitations
Places of action
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article
Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysis
Abstract
Mechanically robust and highly permselective anion exchange membranes (AEMs) were prepared based on a graphene oxide (GO) and polybenzimidazolium nanocomposite. GO was modified via diazonium chemistry for better dispersibility and used to fabricate unsupported, nanocomposite, dense, flat sheet AEMs with different GO loadings. A fabrication route using post-casting methylation was developed to avoid GO aggregation induced by the anion exchange polymer. The even GO distribution in the membranes was mapped by energy dispersive spectroscopy (EDS) and wavelength dispersive spectroscopy (WDS). Tensile testing and nanoindentation showed that the AEMs had great mechanical strength indicated by their high ultimate tensile strength and hardness. Furthermore, the AEMs exhibited high ion exchange capacity (1.7–2.1 mmol g-1), good to exceptional permselectivity (up to 0.99) and relatively low area resistance (down to 2.9 Ω cm2). A trade-off between good selectivity and low resistance was investigated for membranes with low GO loadings (0.25–2.5%). The GO nanocomposite AEMs demonstrated excellent potential for electrodialysis.