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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cseri, Levente
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Tunable 2D Conjugated Porous Organic Polymer Films for Precise Molecular Nanofiltration and Optoelectronicscitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2021Electrospun Adsorptive Nanofibrous Membranes from Ion Exchange Polymers to Snare Textile Dyes from Wastewatercitations
- 2020Metal–Organic Frameworks (MOFs) and MOF-Derived Porous Carbon Materials for Sustainable Adsorptive Wastewater Treatment
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Asymmetric Membrane Capacitive Deionization using Anion-Exchange Membranes based on Quaternized Polymer Blendscitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2020Graphene–PSS/L-DOPA nanocomposite cation exchange membranes for electrodialysis desalinationcitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2019Electrostatically-coupled graphene oxide nanocomposite cation exchange membranecitations
- 2018Robust Covalently Crosslinked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysiscitations
- 2018Robust Covalently Cross-linked Polybenzimidazole/Graphene Oxide Membranes for High-Flux Organic Solvent Nanofiltrationcitations
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article
Graphene oxide – polybenzimidazolium nanocomposite anion exchange membranes for electrodialysis
Abstract
Mechanically robust and highly permselective anion exchange membranes (AEMs) were prepared based on a graphene oxide (GO) and polybenzimidazolium nanocomposite. GO was modified via diazonium chemistry for better dispersibility and used to fabricate unsupported, nanocomposite, dense, flat sheet AEMs with different GO loadings. A fabrication route using post-casting methylation was developed to avoid GO aggregation induced by the anion exchange polymer. The even GO distribution in the membranes was mapped by energy dispersive spectroscopy (EDS) and wavelength dispersive spectroscopy (WDS). Tensile testing and nanoindentation showed that the AEMs had great mechanical strength indicated by their high ultimate tensile strength and hardness. Furthermore, the AEMs exhibited high ion exchange capacity (1.7–2.1 mmol g-1), good to exceptional permselectivity (up to 0.99) and relatively low area resistance (down to 2.9 Ω cm2). A trade-off between good selectivity and low resistance was investigated for membranes with low GO loadings (0.25–2.5%). The GO nanocomposite AEMs demonstrated excellent potential for electrodialysis.