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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Poli, Isabella
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024How Photogenerated I 2 Induces I-Rich Phase Formation in Lead Mixed Halide Perovskitescitations
- 2024How Photogenerated I2 Induces I-Rich Phase Formation in Lead Mixed Halide Perovskitescitations
- 2024Understanding the Surface Chemistry of Tin Halide Perovskitescitations
- 2023Defect Engineering to Achieve Photostable Wide Bandgap Metal Halide Perovskitescitations
- 2023How Photogenerated I2 Induces I‐rich Phase Formation in Lead Mixed Halide Perovskitescitations
- 2023How Halide Alloying Influences the Optoelectronic Quality in Tin-Halide Perovskite Solar Absorberscitations
- 2022Photoluminescence Intensity Enhancement in Tin Halide Perovskitescitations
- 2019Graphite-protected CsPbBr3 perovskite photoanodes functionalised with water oxidation catalyst for oxygen evolution in watercitations
- 2019Inexpensive Metal Free Encapsulation Layers Enable Halide Perovskite Based Photoanodes for Water Splitting
- 2018Screen printed carbon CsPbBr3 solar cells with high open-circuit photovoltagecitations
Places of action
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article
Screen printed carbon CsPbBr3 solar cells with high open-circuit photovoltage
Abstract
<p>Screen printed mesoporous carbon solar cells (mC-PSC) are a promising fully printable technology that does not require organic hole conductors, expensive metal contacts or vacuum processing. However, when infiltrated with the archetypal CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> perovskite, mC-PSCs show low voltage which limits their use in innovative applications such as indoor light harvesting. Here we investigate both planar (C-PSC) and mesoporous (mC-PSC) carbon cells, based on all-inorganic CsPbBr<sub>3</sub>. Pure CsPbBr<sub>3</sub> is a yellow material with an orthorhombic crystal structure at room temperature and a 2.3 eV band gap, which is not ideal for solar cell applications. However, CsPbBr<sub>3</sub> is thermally stable up to over 400 °C and high-voltage planar carbon solar cells, with open circuit voltages of up to 1.29 V and efficiencies up to 6.7% have been reported in the literature. We focus on the effect of the post-annealing temperature on the material properties and photovoltaic activity. XPS and XRD results show a non-linear trend with temperature, with significant improvements in composition between 200 and 300 °C. Both the mesoporous and planar champion devices were obtained after heat processing at 400 °C, reaching PCEs of 8.2% and 5.7% respectively. The average V<sub>oc</sub> for the planar and mesoporous devices were 1.33 V and 1.27 V respectively with a record 1.44 V for the best mC-PSC.</p><p><br/></p><p>This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 665992 </p>