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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Feron, Krishna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2020Fluorination of pyrene-based organic semiconductors enhances the performance of light emitting diodes and halide perovskite solar cellscitations
- 2019Building intermixed donor-acceptor architectures for water-processable organic photovoltaicscitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applicationscitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applications
- 2018Vinylene and benzo[c][1,2,5]thiadiazole: effect of the pi-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistorscitations
- 2018Molecular engineering using an anthanthrone dye for low-cost hole transport materials: A strategy for dopant-free, high-efficiency, and stable perovskite solar cellscitations
- 2018Tunable Crystallization and Nucleation of Planar CH3NH3PbI3 through Solvent-Modified Interdiffusioncitations
- 2017Energy level engineering in ternary organic solar cells: evaluating exciton dissociation at organic semiconductor interfacescitations
Places of action
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article
Vinylene and benzo[c][1,2,5]thiadiazole: effect of the pi-spacer unit on the properties of bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing polymers for n-channel organic field-effect transistors
Abstract
Two polymers based on (3E,7E)-3,7-bis(2-oxoindolin-3-ylidene)benzo[1,2-b:4,5-b′]difuran-2,6(3H,7H)-dione (<b>BIBDF</b>) coupled with (E)-2-(2-(thiophen-2-yl)vinyl)thiophene (TVT) or dithienylbenzothiadiazole (TBT), namely <b>PBIBDF-TVT</b> and <b>PBIBDF-TBT</b> were synthesized via the Stille coupling reaction. The effect of benzothiadiazole or vinylene-π spacer of the copolymers on optical properties, energy levels, electronic device performance and microstructure were studied. It was found that <b>PBIBDF-TBT</b> based OFET devices, annealed at 180 °C, showed better performance with the highest electron mobility of 2.9 × 10<sup>−2</sup> cm<sup>2</sup> V s<sup>−1</sup> whereas <b>PBIBDF-TVT</b> polymer exhibited 5.0 × 10<sup>−4</sup> cm<sup>2</sup> V s<sup>−1</sup>. The two orders of magnitude higher electron mobility of <b>PBIBDF-TBT</b> over <b>PBIBDF-TVT</b> is a clear indicator of the better charge transport ability of this polymer semiconductor arising from its higher crystallinity and better donor–acceptor interaction.