| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cavalaglio, Sébastien
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (2/2 displayed)
- 2022The formulation of a CMC binder/silicon composite anode for Li-ion batteries: from molecular effects of ball milling on polymer chains to consequences on electrochemical performancescitations
- 2019Revisiting and improving the preparation of silicon-based electrodes for lithium-ion batteries: ball milling impact on poly(acrylic acid) polymer binderscitations
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article
Revisiting and improving the preparation of silicon-based electrodes for lithium-ion batteries: ball milling impact on poly(acrylic acid) polymer binders
Abstract
ZnSnSb2 intermetallic alloy as anode material for Li-ion batteries has been investigated for the first time in this work. This material is able to deliver a high capacity of 615 mAh/g for 200 cycles at 4C (a current density of 0.25 A/g) with a good a coulombic efficiency exceeding 99.3 %. Furthermore, the electrode material exhibit a high rate capability between C/5 (12.6 mA/g) and 10C (630 mA/g), with a reversible capacity loss of 19% and a polarization increasing of only 0.05 V. Among all reported MSnSb (with M= Ag, Ti, Cu…) alloys, ZnSnSb2 exhibits the most outstanding rate capability and long cycling life. The observed behavior can be linked not only to the quasi-topotactic de/lithiation reaction between the ZnSnSb2 and Li3Sb but also to the solid solution mechanism evidenced from operando X-ray diffraction analysis. This suggests that the electrode exhibits a great resistance to the volume expansion and the mechanical stress during cycling even at high cycling rates (10C).