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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bose, Ranjita K.
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024Characterizing Dissipative Elastic Metamaterials Produced by Additive Manufacturingcitations
- 2023Oxidative chemical vapor deposition for synthesis and processing of conjugated polymers: A critical reviewcitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Electrically Conductive and Highly Stretchable Piezoresistive Polymer Nanocomposites via Oxidative Chemical Vapor Depositioncitations
- 2023Electrically and thermally healable nanocomposites via one-step Diels-Alder reaction on carbon nanotubescitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Effect of intermolecular interactions on the glass transition temperature of chemically modified alternating polyketonescitations
- 2023Oxidative chemical vapor deposition for synthesis and processing of conjugated polymerscitations
- 2023Oxidative chemical vapor deposition of polypyrrole onto carbon fabric for flexible supercapacitive electrode materialcitations
- 2022All-dry, one-step synthesis, doping and film formation of conductive polypyrrolecitations
- 2022Production and Application of Polymer Foams Employing Supercritical Carbon Dioxidecitations
- 2022Rapid self-healing in IR-responsive plasmonic indium tin oxide/polyketone nanocompositescitations
- 2022Initiated Chemical Vapor Deposition (iCVD) of Bio-Based Poly(tulipalin A) Coatingscitations
- 2022Initiated Chemical Vapor Deposition (iCVD) of Bio-Based Poly(tulipalin A) Coatings:Structure and Material Propertiescitations
- 2021Thermally Switchable Electrically Conductive Thermoset rGO/PK Self-Healing Compositescitations
- 2021Thermally Switchable Electrically Conductive Thermoset rGO/PK Self-Healing Compositescitations
- 2021Self-Healing Polymer Nanocomposite Materials by Joule Effectcitations
- 2021Polytriphenylamine composites for energy storage electrodescitations
- 2020Highly Branched Waxy Potato Starch-Based Polyelectrolyte:Controlled Synthesis and the Influence of Chain Composition on Solution Rheologycitations
- 2020Highly Branched Waxy Potato Starch-Based Polyelectrolytecitations
- 2019Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bondscitations
- 2019Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bondscitations
- 2018A translation of the structure of mussel byssal threads into synthetic materials by the utilization of histidine-rich block copolymerscitations
- 2016Healing by the Joule effect of electrically conductive poly(ester-urethane)/carbon nanotube nanocompositescitations
- 2016Healing of early stage fatigue damage in ionomer/Fe3O4 nanoparticle compositescitations
- 2015Connecting supramolecular bond lifetime and network mobility for scratch healing in poly(butyl acrylate) ionomers containing sodium, zinc and cobaltcitations
- 2015Correlation between scratch healing and rheological behavior for terpyridine complex based metallopolymerscitations
- 2015Acylhydrazones as reversible covalent crosslinkers for self-healing polymerscitations
- 2012Microencapsulation of a crop protection compound by initiated chemical vapor depositioncitations
- 2012Polymer electronic materials for sustainable energies
- 2012Graft polymerization of anti-fouling PEO surfaces by liquid-free initiated chemical vapor depositioncitations
- 2009Initiated chemical vapor deposition (iCVD) of hydrogel polymerscitations
Places of action
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article
A translation of the structure of mussel byssal threads into synthetic materials by the utilization of histidine-rich block copolymers
Abstract
<p>Mussel byssal threads are well-known due to their self-healing ability after the mechanical stress caused by waves. The proposed mechanism demonstrates the importance of reversible histidine-metal interactions as well as the block copolymer-like hierarchical architecture of the underlying protein structure. Taking these two aspects as inspiration for the design of synthetic analogs, different histidine-rich block copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The hard domain was mimicked using polystyrene and the soft domain consists of n-butyl acrylate (BA) as well as histidine moieties as ligands. The block copolymers were crosslinked using different zinc(ii) salts and the resulting metallopolymers were investigated with respect to their self-healing abilities. The observed two-step mechanism of the self-healing process was studied in detail. Furthermore, the mechanical properties were determined by nanoindentation and were correlated with other results.</p>