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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Litvin, Aleksandr P.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Near-infrared two-photon excited photoluminescence from Yb3+-doped CsPbClxBr3−x perovskite nanocrystals embedded into amphiphilic silica microspherescitations
- 2023Anion-assisted Yb3+ and Mn2+ doping of 0D and 2D lead halide perovskite nanostructurescitations
- 2021Carbon Nanoparticles as Versatile Auxiliary Components of Perovskite-Based Optoelectronic Devicescitations
- 2020Tunable Mie Resonances of Tin-based Iodide Perovskite Islandlike Films with Enhanced Infrared Photoluminescencecitations
- 2019Ternary Composites with PbS Quantum Dots for Hybrid Photovoltaicscitations
- 20183D superstructures with an orthorhombic lattice assembled by colloidal PbS quantum dotscitations
- 2017Photoluminescence of Lead Sulfide Quantum Dots of Different Sizes in a Nanoporous Silicate Glass Matrixcitations
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article
3D superstructures with an orthorhombic lattice assembled by colloidal PbS quantum dots
Abstract
We report a new type of metamaterial comprising a highly ordered 3D network of 3-7 nm lead sulfide quantum dots self-assembled in an organic matrix formed by amphiphilic ligands (oleic acid molecules). The obtained 3D superstructures possess an orthorhombic lattice with the distance between the nanocrystals as large as 10-40 nm. Analysis of self-assembly and destruction of the superstructures in time performed by a SAXS technique shows that their morphology depends on the quantity of amphiphilic ligands and width of the quantum dot size and its distribution. Formation of the superstructures is discussed in terms of a model describing the lyotropic crystal formation by micelles from three-phase mixtures. The results show that the organic molecules possessing surfactant properties and capable of forming micelles with nanoparticles as a micelle core can be utilized as building blocks for the creation of novel metamaterials based on a highly ordered 3D network of semiconductors, metals or magnetic nanoparticles.