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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Richardson, Giles
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Deducing transport properties of mobile vacancies from perovskite solar cell characteristicscitations
- 2020Identification of recombination losses and charge collection efficiency in a perovskite solar cell by comparing impedance response to a drift-diffusion modelcitations
- 2019How transport layer properties affect perovskite solar cell performancecitations
- 2019How transport layer properties affect perovskite solar cell performance: insights from a coupled charge transport/ion migration modelcitations
- 2017Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cellscitations
- 2017A mathematical model for mechanically-induced deterioration of the binder in lithium-ion electrodescitations
- 2016Drift diffusion modelling of charge transport in photovoltaic devicescitations
- 2015Improving the Long-Term Stability of Perovskite Solar Cells with a Porous Al O Buffer Layercitations
- 2009An asymptotic analysis of the buckling of a highly shear-resistant vesiclecitations
- 2000The mixed boundary condition for the Ginzburg Landau model in thin filmscitations
Places of action
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article
How transport layer properties affect perovskite solar cell performance
Abstract
<p>The effects of transport layers on perovskite solar cell performance, in particular anomalous hysteresis, are investigated. A model for coupled ion vacancy motion and charge transport is formulated and solved in a three-layer planar perovskite solar cell. Its results are used to demonstrate that the replacement of standard transport layer materials (spiro-OMeTAD and TiO<sub>2</sub>) by materials with lower permittivity and/or doping leads to a shift in the scan rates at which hysteresis is most pronounced to rates higher than those commonly used in experiment. These results provide a cogent explanation for why organic electron transport layers can yield seemingly "hysteresis-free" devices but which nevertheless exhibit hysteresis at low temperature. In these devices the decrease in ion vacancy mobility with temperature compensates for the increase in hysteresis rate with use of low permittivity/doping organic transport layers. Simulations are used to classify features of the current-voltage curves that distinguish between cells in which charge carrier recombination occurs predominantly at the transport layer interfaces and those where it occurs predominantly within the perovskite. These characteristics are supplemented by videos showing how the electric potential, electronic and ionic charge profiles evolve across a planar perovskite solar cell during a current-voltage scan. Design protocols to mitigate the possible effects of high ion vacancy distributions on cell degradation are discussed. Finally, features of the steady-state potential profile for a device held near the maximum power point are used to suggest ways in which interfacial recombination can be reduced, and performance enhanced, via tuning transport layer properties.</p>